Material characterization of recycled and virgin carbon fibers for transportation composites lightweighting

被引:25
作者
Maia, Bruno Sena [1 ]
Tjong, Jimi [3 ]
Sain, Mohini [2 ,3 ]
机构
[1] Univ Toronto, Fac Forestry, Ctr Biocomposites & Biomat Proc, 33 Willcocks St, Toronto, ON M5S 3B3, Canada
[2] Beijing Univ Chem Technol, Dept Mat & Mfg, North Third Ring Rd 15, Beijing 100029, Peoples R China
[3] Univ Toronto, Dept Mech & Ind Engn, 5 Kings Coll Rd, Toronto, ON M5S 3G8, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Carbon fiber; Lightweighting; Composites; TGA; XPS; FTIR; REINFORCED POLYMERS; CFRP; ADHESION; XPS;
D O I
10.1016/j.mtsust.2019.100011
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Research results revealed that controlled thermal re-exposure of preconsumed recycled carbon fiber (RCF) increases the formation of a graphitic core and consequently a higher modulus recycled carbon fiber. Furthermore, formation of acidic functionality on carbon during thermal treatment led to improved adhesion with plastic. Transportation lightweighting is shaping the future of mobility and becomes focus of many original equipment manufacturers (OEMs) for many segments as an answer for efficient products. Thermogravimetric analysis (TGA) showed that RCF can resist temperatures up to 400 degrees C without surface degradation, 50 degrees C lower than virgin carbon fiber (VCF), and total treatment weight loss was measured. Fourier-transform infrared spectroscopy (FTIR) results showed acidic groups on thermally treated RCF surface that improved chemical adhesion compared with non-treated RCF. Finally, X-ray photoelectron spectroscopy (XPS) showed the oxygen/carbon ratios, and its perspective deconvolutions were compared with FTIR results. Lower C1s content was found on RCF structure because of thermal treatment. XPS results evidenced the formation of aromatic carbon rings during thermal treatment, further supported by thermogravimetric results. Thus, the thermal process promoted increase in the formation of a graphitic core and consequently a higher modulus RCF. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页数:13
相关论文
共 35 条
[1]   Recycled carbon fibre-reinforced polypropylene thermoplastic composites [J].
Akonda, M. H. ;
Lawrence, C. A. ;
Weager, B. M. .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2012, 43 (01) :79-86
[2]   Thermal, Electrical and Surface Hydrophobic Properties of Electrospun Polyacrylonitrile Nanofibers for Structural Health Monitoring [J].
Alarifi, Ibrahim M. ;
Alharbi, Abdulaziz ;
Khan, Waseem S. ;
Swindle, Andrew ;
Asmatulu, Ramazan .
MATERIALS, 2015, 8 (10) :7017-7031
[3]  
[Anonymous], 2011, INT J LIFE CYCLE ASS, DOI DOI 10.1007/S11367-011-0264-Z
[4]  
[Anonymous], 2017, LIGHTWEIGHT SUSTAINA
[5]  
Bromley J., 1971, Proc. International Carbon Fiber Conference, P3
[6]  
Connor M.L., 2008, Characterization of Recycled Carbon Fibers and Their Formation of Composites Using Injection Molding
[7]   A Novel Sonochemical Approach for Enhanced Recovery of Carbon Fiber from CFRP Waste Using Mild Acid-Peroxide Mixture [J].
Das, Mohan ;
Varughese, Susy .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2016, 4 (04) :2080-2087
[8]  
Das S., 2016, CONTRACT, DOI [10.2172/1254094, DOI 10.2172/1254094]
[9]   Carbon Fibers: Precursors, Manufacturing, and Properties [J].
Frank, Erik ;
Hermanutz, Frank ;
Buchmeiser, Michael R. .
MACROMOLECULAR MATERIALS AND ENGINEERING, 2012, 297 (06) :493-501
[10]  
Gardiner Ginger, Recycled carbon fiber update: Closing the CFRP lifecycle loop