Boron trifluoride-etherate induced rearrangement of bicyclo[2.2.2]octenediones: An efficient synthesis of bicyclo[3.2.1]octenediones

被引:1
作者
Nair, V [1 ]
Maliakal, D
Treesa, PM
Anilkumar, G
Vairamani, M
Prabhakar, S
Rath, NP
机构
[1] CSIR, Reg Res Lab, Div Organ Chem, Trivandrum 695019, Kerala, India
[2] Indian Inst Chem Technol, Div Analyt Chem, Hyderabad 500007, Andhra Pradesh, India
[3] Univ Missouri, Dept Chem, St Louis, MO 63121 USA
关键词
bicyclic aliphatic compounds; diones; rearrangements;
D O I
10.1016/S0040-4020(00)00275-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A facile transformation of bicyclo[2.2.2]octenediones to bicyclo[3.2.l]octenediones mediated by BF3-etherate is described. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3735 / 3741
页数:7
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