Self-Assembled Supramolecular Structures as Catalysts for Reactions Involving Cationic Transition States

被引：31

作者：

Catti, Lorenzo ^{[1
]}

Zhang, Qi ^{[1
]}

Tiefenbacher, Konrad ^{[1
]}

机构：

[1] Tech Univ Munich, Dept Chem, Lichtenbergstr 4, D-85747 Garching, Germany

来源：

SYNTHESIS-STUTTGART | 2016年 / 48卷 / 03期

关键词：

catalysis; supramolecular chemistry; carbocation; self-assembly; enzyme mimicry; HEXAMERIC RESORCINARENE CAPSULE; AZA-COPE REARRANGEMENT; METAL-LIGAND CLUSTER; BASIC SOLUTION; NAZAROV CYCLIZATION; DIFFUSION NMR; REVERSIBLE ENCAPSULATION; ORTHOFORMATE HYDROLYSIS; TERPENE BIOSYNTHESIS; MECHANISTIC INSIGHTS;

D O I：

10.1055/s-0035-1560362

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Self-assembled supramolecular structures represent easily accessible systems for the study of enzyme-like catalysis. The hydrophobic cavities of the assemblies provide a distinct chemical environment that can lead to unusual chemo-and stereoselectivities. This review summarizes the application of such host structures in the catalysis of reactions involving cationic transition states and includes detailed discussion of mechanisms and substrate-host interactions. The literature up to April 2015 is covered. 1 Introduction 2 Molecular Capsules: Structures and Background 3 Catalyzed Reactions 4 Summary and Outlook

引用

页码：313 / 328

页数：16

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