Stable and bright formamidinium-based perovskite light-emitting diodes with high energy conversion efficiency

被引:126
作者
Miao, Yanfeng [1 ,2 ]
Ke, You [1 ,2 ]
Wang, Nana [1 ,2 ]
Zou, Wei [1 ,2 ]
Xu, Mengmeng [1 ,2 ]
Cao, Yu [1 ,2 ]
Sun, Yan [1 ,2 ]
Yang, Rong [1 ,2 ]
Wang, Ying [1 ,2 ]
Tong, Yunfang [1 ,2 ]
Xu, Wenjie [1 ,2 ]
Zhang, Liangdong [1 ,2 ]
Li, Renzhi [1 ,2 ]
Li, Jing [3 ]
He, Haiping [3 ]
Jin, Yizheng [4 ,5 ]
Gao, Feng [6 ]
Huang, Wei [1 ,2 ,7 ,8 ,9 ]
Wang, Jianpu [1 ,2 ]
机构
[1] Nanjing Tech Univ NanjingTech, Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, KLOFE, 30 South Puzhu Rd, Nanjing 211816, Jiangsu, Peoples R China
[2] Nanjing Tech Univ NanjingTech, Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, Inst Adv Mat, 30 South Puzhu Rd, Nanjing 211816, Jiangsu, Peoples R China
[3] Zhejiang Univ, Sch Mat Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
[4] Zhejiang Univ, Ctr Chem High Performance & Novel Mat, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
[5] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
[6] Linkoping Univ, IFM, Biomol & Organ Elect, S-58183 Linkoping, Sweden
[7] Nanjing Univ Posts & Telecommun, Key Lab Organ Elect & Informat Displays, Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, 9 Wenyuan Rd, Nanjing 210023, Jiangsu, Peoples R China
[8] Nanjing Univ Posts & Telecommun, Inst Adv Mat, Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, 9 Wenyuan Rd, Nanjing 210023, Jiangsu, Peoples R China
[9] Northwestern Polytech Univ, Shaanxi Inst Flexible Elect, 127 West Youyi Rd, Xian 710072, Shaanxi, Peoples R China
基金
中国国家自然科学基金; 国家重点研发计划;
关键词
PASSIVATION;
D O I
10.1038/s41467-019-11567-1
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Solution-processable perovskites show highly emissive and good charge transport, making them attractive for low-cost light-emitting diodes (LEDs) with high energy conversion efficiencies. Despite recent advances in device efficiency, the stability of perovskite LEDs is still a major obstacle. Here, we demonstrate stable and bright perovskite LEDs with high energy conversion efficiencies by optimizing formamidinium lead iodide films. Our LEDs show an energy conversion efficiency of 10.7%, and an external quantum efficiency of 14.2% without outcoupling enhancement through controlling the concentration of the precursor solutions. The device shows low efficiency droop, i.e. 8.3% energy conversion efficiency and 14.0% external quantum efficiency at a current density of 300 mA cm(-2), making the device more efficient than state-of-the-art organic and quantum-dot LEDs at high current densities. Furthermore, the half-lifetime of device with benzylamine treatment is 23.7 hr under a current density of 100 mA cm(-2), comparable to the lifetime of near-infrared organic LEDs.
引用
收藏
页数:7
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