Synthesis, crystal structure and optical property of two zinc metal organic frameworks constructed from isonicotinic acid

被引：10

作者：

Xiao, Yi-Fan ^{[1
]}

Wang, Ting-Ting ^{[1
]}

Zeng, He-ping ^{[1
]}

机构：

[1] S China Univ Technol, Sch Chem & Chem Engn, State Key Lab Luminescent Mat, Guangzhou 510641, Guangdong, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2014年 / 1074卷

基金：

中国国家自然科学基金;

关键词：

Metal Organic Frameworks; Zn complex; Isonicotinic acid; Crystal structure; Isomer; COORDINATION POLYMERS; HYDROTHERMAL SYNTHESIS; MIXED-LIGANDS; LN; EU;

D O I：

10.1016/j.molstruc.2014.06.018

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two new zinc Metal Organic Frameworks(MOFs), Zn(IN)(2) (1) and Zn(IN)(2)(NO3)(H2O) (2)(HIN = isonicotinic acid), have been synthesized and characterized by PXRD,IR, BET surface area test, uv-vis spectra, thermogravimetric analysis, fluorescent Spectra and single crystal X-ray diffraction. 1 is a 3D 3-fold interpenetrating framework. While 2 reveals a 1D chain structure. Different structures resulted in different optical properties. And there was a crystal phase transformation for 2 when it actived at 100 degrees C. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：330 / 338

页数：9

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