Effect of excess Li2S on electrochemical properties of amorphous li3ps4 films synthesized by pulsed laser deposition

被引：21
作者：
Quan, Zhen [1 ]
Hirayama, Masaaki [1 ]
Sato, Daichi [1 ]
Zheng, Yueming [1 ]
Yano, Taka-aki [1 ]
Hara, Kosuke [1 ]
Suzuki, Kota [1 ]
Hara, Masahiko [1 ]
Kanno, Ryoji [1 ]
机构：
[1] Tokyo Inst Technol, Sch Mat & Chem Technol, Dept Chem Sci & Engn, Midori Ku, Yokohama, Kanagawa, Japan
来源：
JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2017年 / 100卷 / 02期
基金：
日本学术振兴会;
关键词：
lithium ion conductivity; solid electrolyte; solid state batteries; thin-film; LITHIUM IONIC CONDUCTOR; SOLID-STATE BATTERY; THIO-LISICON; GLASS-CERAMICS; SYSTEM; ELECTROLYTE; LI2S-P2S5; OXIDE; INTERCALATION; INTERFACE;
D O I：
10.1111/jace.14579
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Amorphous Li3PS4 films were synthesized by pulsed laser deposition (PLD) at room temperature using Li3PS4 targets with excess lithium and sulfur. Raman and X-ray photoemission spectroscopies indicated that the Li3PS4 film synthesized with a stoichiometric amount of Li3PS4 target contained lithium-deficient phases such as Li4P2S6, Li2-xS and sulfur due to composition deviation caused during the ablation process. The film synthesized with a 14% Li2S-excess target (Li3.42PS4.21) contained fewer impurities, and exhibited a higher ionic conductivity of 5.3x10(-4)S/cm at 298K than the lithium-deficient film (3.1x10(-4)S/cm). The target composition is an important factor for the fabrication of highly conductive Li3PS4 films for electrolytes in thin-film batteries.
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收藏
页码：746 / 753
页数：8
相关论文
共 34 条
[1]   A fully integrated microbattery for an implantable microelectromechanical system [J].
Albano, F. ;
Lin, Y. S. ;
Blaauw, D. ;
Sylvester, D. M. ;
Wise, K. D. ;
Sastry, A. M. .
JOURNAL OF POWER SOURCES, 2008, 185 (02) :1524-1532
[2]   Understanding the Nature of Absorption/Adsorption in Nanoporous Polysulfide Sorbents for the Li-S Battery [J].
Evers, Scott ;
Yim, Taeeun ;
Nazar, Linda F. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (37) :19653-19658
[3]   Negligible "Negative Space-Charge Layer Effects" at Oxide-Electrolyte/Electrode Interfaces of Thin-Film Batteries [J].
Haruta, Masakazu ;
Shiraki, Susumu ;
Suzuki, Tohru ;
Kumatani, Akichika ;
Ohsawa, Takeo ;
Takagi, Yoshitaka ;
Shimizu, Ryota ;
Hitosugi, Taro .
NANO LETTERS, 2015, 15 (03) :1498-1502
[4]   Space-Charge Layer Effect at Interface between Oxide Cathode and Sulfide Electrolyte in All-Solid-State Lithium-Ion Battery [J].
Haruyama, Jun ;
Sodeyama, Keitaro ;
Han, Liyuan ;
Takada, Kazunori ;
Tateyama, Yoshitaka .
CHEMISTRY OF MATERIALS, 2014, 26 (14) :4248-4255
[5]   Characterization of electrode/electrolyte interface using in situ X-ray reflectometry and LiNi0.8Co0.2O2 epitaxial film electrode synthesized by pulsed laser deposition method [J].
Hirayama, Masaaki ;
Sakamoto, Kazuyuki ;
Hiraide, Tetsuya ;
Mori, Daisuke ;
Yamada, Atsuo ;
Kanno, Ryoji ;
Sonoyama, Noriyuki ;
Tamura, Kazuhisa ;
Mizuki, Jun'ichiro .
ELECTROCHIMICA ACTA, 2007, 53 (02) :871-881
[6]   Structural and electrolyte properties of Li4P2S6 [J].
Hood, Zachary D. ;
Kates, Cameron ;
Kirkham, Melanie ;
Adhikari, Shiba ;
Liang, Chengdu ;
Holzwarth, N. A. W. .
SOLID STATE IONICS, 2016, 284 :61-70
[7]   Application of LiCoO2 Particles Coated with Lithium Ortho-Oxosalt Thin Films to Sulfide-Type All-Solid-State Lithium Batteries [J].
Ito, Yusuke ;
Sakurai, Yuki ;
Yubuchi, So ;
Sakuda, Atsushi ;
Hayashi, Akitoshi ;
Tatsumisago, Masahiro .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2015, 162 (08) :A1610-A1616
[8]   Li4GeS4-Li3PS4 electrolyte thin films with highly ion-conductive crystals prepared by pulsed laser deposition [J].
Ito, Yusuke ;
Sakuda, Atsushi ;
Ohtomo, Takamasa ;
Hayashi, Akitoshi ;
Tatsumisago, Masahiro .
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2014, 122 (1425) :341-345
[9]  
Kamaya N, 2011, NAT MATER, V10, P682, DOI [10.1038/NMAT3066, 10.1038/nmat3066]
[10]   Lithium ionic conductor thio-LISICON -: The Li2S-GeS2-P2S5 system [J].
Kanno, R ;
Maruyama, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (07) :A742-A746
1234