Iron(II)-Catalyzed Direct Cyanation of Arenes with Aryl(cyano)iodonium Triflates

被引：105
|
作者：
Shu, Zhibin [1 ,2 ]
Ji, Wenzhi [1 ,2 ]
Wang, Xi [1 ,2 ]
Zhou, Yujing [1 ,2 ]
Zhang, Yan [1 ,2 ]
Wang, Jianbo [1 ,2 ,3 ]
机构：
[1] Peking Univ, BNLMS, Beijing 100871, Peoples R China
[2] Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China
[3] Chinese Acad Sci, SIOC, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 08期
关键词：
aromatic substitution; aryl nitriles; cyanation; hypervalent iodine; iron catalysis; PALLADIUM-CATALYZED CYANATION; IODINE(III) BIS(TRIFLUOROACETATE) PIFA; C-H CYANATION; AROMATIC NITRILES; PHENOL ETHERS; ARYL HALIDES; ELECTROPHILIC CYANATION; CONVENIENT PROCEDURE; MEDIATED CYANATION; GENERAL-APPROACH;
D O I：
10.1002/anie.201309791
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A direct oxidative cyanation of arenes under Fe-II catalysis with 3,5-di(trifluoromethyl)phenyl(cyano)iodonium triflate (DFCT) as the cyanating agent has been developed. The reaction is applicable to wide range of aromatic substrates, including polycyclic structures and heteroaromatic compounds.
引用
收藏
页码：2186 / 2189
页数：4
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