Characterization of Intermediate Oxidation States in CO2 Activation

被引：71

作者：

Dodson, Leah G. ^{[1
,2
]}

Thompson, Michael C. ^{[1
,3
]}

Weber, J. Mathias ^{[1
,3
]}

机构：

[1] Univ Colorado, JILA, Boulder, CO 80309 USA

[2] Univ Colorado, NIST, Boulder, CO 80309 USA

[3] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

来源：

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, VOL 69 | 2018年 / 69卷

基金：

美国国家科学基金会;

关键词：

carbon dioxide; formate; oxalate; carbonate; C-O activation; CO2 reduction catalysis; INFRARED PHOTODISSOCIATION SPECTROSCOPY; CARBON-DIOXIDE ACTIVATION; DRIVEN REDUCTIVE ACTIVATION; ELECTROCHEMICAL REDUCTION; VIBRATIONAL-SPECTRA; GAS-PHASE; PHOTOELECTRON-SPECTROSCOPY; MATRIX-ISOLATION; ELECTROCATALYTIC REDUCTION; COORDINATION CHEMISTRY;

D O I：

10.1146/annurev-physchem-050317-021122

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Redox chemistry during the activation of carbon dioxide involves changing the charge state in a CO2 molecular unit. However, such changes are usually not well described by integer formal charges, and one can think of COO functional units as being in intermediate oxidation states. In this article, we discuss the properties of CO2 and CO2-based functional units in various charge states. Besides covering isolated CO2 and its ions, we describe the CO2-based ionic species formate, oxalate, and carbonate. Finally, we provide an overview of CO2-based functional groups and ligands in clusters and metal-organic complexes.

引用

页码：231 / 252

页数：22

共 152 条

[11] Catalysis of the electrochemical reduction of carbon dioxide by iron(O) porphyrins: Synergystic effect of weak Bronsted acids [J].

Bhugun, I ;

Lexa, D ;

Saveant, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (07) :1769-1776

[12] THE PHOTOELECTROCATALYTIC REDUCTION OF CARBON-DIOXIDE [J].

BOCKRIS, JO ;

WASS, JC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (09) :2521-2528

[13] Small multiply charged anions as building blocks in chemistry [J].

Boldyrev, AI ;

Gutowski, M ;

Simons, J .

ACCOUNTS OF CHEMICAL RESEARCH, 1996, 29 (10) :497-502

[14] CARBON-DIOXIDE COORDINATION CHEMISTRY .5. THE PREPARATION AND STRUCTURE OF RH(ETA-1-CO2)(CL)(DIARS)2 [J].

CALABRESE, JC ;

HERSKOVITZ, T ;

KINNEY, JB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (18) :5914-5915

[15] ELECTRONIC ABSORPTION SPECTRA OF CO2-TRAPPED IN GAMMA-IRRADIATED CRYSTALLINE SODIUM FORMATE [J].

CHANTRY, GW ;

WHIFFEN, DH .

MOLECULAR PHYSICS, 1962, 5 (02) :189-194

[16] Raman, infrared and force field studies of K212C2O4•H2O and K213C2O4•H2O in the solid state and in aqueous solution, and of (NH4)212C2O4•H2O and (NH4)212C2O4•H2O in the solid state [J].

Clark, RJH ;

Firth, S .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2002, 58 (08) :1731-1746

[17] COLLISIONAL IONIZATION OF NA, K, AND CS BY CO2, COS, AND CS2 - MOLECULAR ELECTRON AFFINITIES [J].

COMPTON, RN ;

REINHARDT, PW ;

COOPER, CD .

JOURNAL OF CHEMICAL PHYSICS, 1975, 63 (09) :3821-3827

[18] Catalysis of the electrochemical reduction of carbon dioxide [J].

Costentin, Cyrille ;

Robert, Marc ;

Saveant, Jean-Michel .

CHEMICAL SOCIETY REVIEWS, 2013, 42 (06) :2423-2436

[19] A Vibrational-Spectroscopic Study of the Species Present in the CO(2)-H(2)O System [J].

Davis, A. R. ;

Oliver, B. G. .

JOURNAL OF SOLUTION CHEMISTRY, 1972, 1 (04) :329-339

[20] The Oxalate Dianion, C2O42-: Planar or Nonplanar? [J].

Dean, Philip A. W. .

JOURNAL OF CHEMICAL EDUCATION, 2012, 89 (03) :417-418

← 1 2 3 4 5 6 7 8 9 10 →