Characterization of Intermediate Oxidation States in CO2 Activation

被引：71

作者：

Dodson, Leah G. ^{[1
,2
]}

Thompson, Michael C. ^{[1
,3
]}

Weber, J. Mathias ^{[1
,3
]}

机构：

[1] Univ Colorado, JILA, Boulder, CO 80309 USA

[2] Univ Colorado, NIST, Boulder, CO 80309 USA

[3] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

来源：

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, VOL 69 | 2018年 / 69卷

基金：

美国国家科学基金会;

关键词：

carbon dioxide; formate; oxalate; carbonate; C-O activation; CO2 reduction catalysis; INFRARED PHOTODISSOCIATION SPECTROSCOPY; CARBON-DIOXIDE ACTIVATION; DRIVEN REDUCTIVE ACTIVATION; ELECTROCHEMICAL REDUCTION; VIBRATIONAL-SPECTRA; GAS-PHASE; PHOTOELECTRON-SPECTROSCOPY; MATRIX-ISOLATION; ELECTROCATALYTIC REDUCTION; COORDINATION CHEMISTRY;

D O I：

10.1146/annurev-physchem-050317-021122

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Redox chemistry during the activation of carbon dioxide involves changing the charge state in a CO2 molecular unit. However, such changes are usually not well described by integer formal charges, and one can think of COO functional units as being in intermediate oxidation states. In this article, we discuss the properties of CO2 and CO2-based functional units in various charge states. Besides covering isolated CO2 and its ions, we describe the CO2-based ionic species formate, oxalate, and carbonate. Finally, we provide an overview of CO2-based functional groups and ligands in clusters and metal-organic complexes.

引用

页码：231 / 252

页数：22

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