Comparative study of the impact and sliding behavior of water droplets on two different hydrophobic silane coatings

被引:22
作者
Nakajima, Akira [1 ,2 ]
Miyamoto, Takumi [1 ]
Sakai, Munetoshi [2 ]
Isobe, Toshihiro [1 ]
Matsushita, Sachiko [1 ]
机构
[1] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Met & Ceram Sci, Meguro Ku, Tokyo 1528552, Japan
[2] Kanagawa Acad Sci & Technol, Takatsu Ku, Kawasaki, Kanagawa 2130012, Japan
关键词
Hydrophobic; Silane; Impact; Sliding; Dynamic; SELF-ASSEMBLED MONOLAYERS; PROBE FORCE MICROSCOPY; DEFORMATION; DYNAMICS; SURFACES;
D O I
10.1016/j.apsusc.2013.12.097
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Smooth hydrophobic silane coatings were prepared on a Si substrate using ODS (CH3(CH2)(17)Si(OCH3)(3) and FAS17 (CF3(CF2)(7)(CH2)(2)Si(OCH3)(3)). Results obtained using ellipsometry and Kelvin force microscopy suggest that ODS molecules in the coating are tilting or inflected, whereas those of FAS17 are more normal to the substrate. Impact and sliding behaviors of water droplets on the respective surfaces were investigated using a 15 mu L water droplet by varying the droplet release height. Droplets on ODS slid down faster than on FAS17 when released from 0 mm height (i.e. traditional dynamic hydrophobicity measurement). The order was reversed when providing the impact velocity. Comparison of energy dissipation during the impact process revealed that the droplet on ODS, because of its large deformation, loses more energy than that on FAS17. These results demonstrate that the order of droplet removal performance depends on the presence or absence of some initial velocity. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:990 / 996
页数:7
相关论文
共 37 条
[1]  
ASAI A, 1993, J IMAGING SCI TECHN, V37, P205
[2]   Chain length effect of alkanethiol self-assembled monolayers on the maximum spreading ratio of impacting water droplets [J].
Chang, YW ;
Ukiwe, C ;
Kwok, DY .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2005, 260 (1-3) :255-263
[3]   Effects of tangential speed on low-normal-speed liquid drop impact on a non-wettable solid surface [J].
Chen, RH ;
Wang, HW .
EXPERIMENTS IN FLUIDS, 2005, 39 (04) :754-760
[4]   Maximal deformation of an impacting drop [J].
Clanet, C ;
Béguin, C ;
Richard, D ;
Quéré, D .
JOURNAL OF FLUID MECHANICS, 2004, 517 :199-208
[5]   Study of liquid droplets impact on dry inclined surface [J].
Cui, Jie ;
Chen, Xueli ;
Wang, Fuchen ;
Gong, Xin ;
Yu, Zunhong .
ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, 2009, 4 (05) :643-648
[6]   Sliding of Water Droplets on Hydrophobic Surfaces with Various Hydrophilic Region Sizes [J].
Furuta, Tsutomu ;
Sakai, Munetoshi ;
Isobe, Toshihiro ;
Matsushita, Sachiko ;
Nakajima, Akira .
LANGMUIR, 2011, 27 (11) :7307-7313
[7]   Evaporation and Sliding of Water Droplets on Fluoroalkylsilane Coatings with Nanoscale Roughness [J].
Furuta, Tsutomu ;
Nakajima, Akira ;
Sakai, Munetoshi ;
Isobe, Toshihiro ;
Kameshima, Yoshikazu ;
Okada, Kiyoshi .
LANGMUIR, 2009, 25 (10) :5417-5420
[8]   EXPERIMENTAL-STUDY OF SPRAY COOLING WITH FREON-113 [J].
GHODBANE, M ;
HOLMAN, JP .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 1991, 34 (4-5) :1163-1174
[9]   LIQUID SPRAY COOLING OF A HEATED SURFACE [J].
GRISSOM, WM ;
WIERUM, FA .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 1981, 24 (02) :261-271
[10]   A MATHEMATICAL-MODEL OF THE SPRAY DEPOSITION PROCESS [J].
GUTIERREZMIRAVETE, E ;
LAVERNIA, EJ ;
TRAPAGA, GM ;
SZEKELY, J ;
GRANT, NJ .
METALLURGICAL TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1989, 20 (01) :71-85