Efficient rhenium-catalyzed photochemical carbon dioxide reduction under high pressure

被引：30

作者：

Hori, H ^{[1
]}

Takano, Y ^{[1
]}

Koike, K ^{[1
]}

Sasaki, Y ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, AIST, Tsukuba, Ibaraki 3058569, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 03期

关键词：

high pressure; carbon dioxide; rhenium; photocatalyst;

D O I：

10.1016/S1387-7003(02)00758-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The photocatalytic reduction of CO2-to-CO was carried out under high pressure with [fac-Re(bpy)(CO)(3)Cl] (bpy=2,2'-bipyridine) as the catalyst. The use of high-pressure CO2 gas was much more effective than the addition of excess Cl- ions for increasing the stability of the catalyst and achieving efficient CO formation. The turnover number for CO formation at 2.45 MPa of CO, reached a maximum of 41.8, which was 5.1 times the turnover number for the conventional normal-pressure system. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：300 / 303

页数：4

共 16 条

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