Photochemical addition of silirane to endohedral metallofullerene: Electronic properties of carbosilylated Sc3N@lh-C80

被引：6

作者：

Kako, Masahiro ^{[1
]}

Sugiura, Takeshi ^{[1
]}

Akasaka, Takeshi ^{[2
,3
,4
,5
]}

机构：

[1] Univ Electrocommun, Dept Engn Sci, Chofu, Tokyo 1828585, Japan

[2] Univ Tsukuba, Tsukuba Adv Res Alliance, Life Sci Ctr, Ibaraki, Japan

[3] Tokyo Gakugei Univ, Dept Chem, Tokyo, Japan

[4] Fdn Adv Int Sci, Ibaraki, Japan

[5] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, Wuhan 430074, Peoples R China

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2016年 / 191卷 / 02期

关键词：

Endohedral metallofullerene; silirane; carbosilylation; redox potential; ELECTROCHEMICAL PROPERTIES; M3N-AT-C-80; M; SC; REACTIVITY; ISOMERS; ATOMS;

D O I：

10.1080/10426507.2015.1079196

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The photochemical reaction of Sc3N@I-h-C-80 with silirane 1 produced the corresponding carbosilylated derivatives. The electrochemical studies of [5,6]-adducts indicate that carbosilylation is an effective method for tuning moderately the electronic characteristics of Sc3N@I-h-C-80. Density functional theory calculations were also conducted to offer a theoretical basis for the electronic properties of carbosilylated derivatives.

引用

页码：201 / 206

页数：6