Photochemical addition of silirane to endohedral metallofullerene: Electronic properties of carbosilylated Sc3N@lh-C80

被引：6

作者：

Kako, Masahiro ^{[1
]}

Sugiura, Takeshi ^{[1
]}

Akasaka, Takeshi ^{[2
,3
,4
,5
]}

机构：

[1] Univ Electrocommun, Dept Engn Sci, Chofu, Tokyo 1828585, Japan

[2] Univ Tsukuba, Tsukuba Adv Res Alliance, Life Sci Ctr, Ibaraki, Japan

[3] Tokyo Gakugei Univ, Dept Chem, Tokyo, Japan

[4] Fdn Adv Int Sci, Ibaraki, Japan

[5] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, Wuhan 430074, Peoples R China

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2016年 / 191卷 / 02期

关键词：

Endohedral metallofullerene; silirane; carbosilylation; redox potential; ELECTROCHEMICAL PROPERTIES; M3N-AT-C-80; M; SC; REACTIVITY; ISOMERS; ATOMS;

D O I：

10.1080/10426507.2015.1079196

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The photochemical reaction of Sc3N@I-h-C-80 with silirane 1 produced the corresponding carbosilylated derivatives. The electrochemical studies of [5,6]-adducts indicate that carbosilylation is an effective method for tuning moderately the electronic characteristics of Sc3N@I-h-C-80. Density functional theory calculations were also conducted to offer a theoretical basis for the electronic properties of carbosilylated derivatives.

引用

页码：201 / 206

页数：6

共 39 条

[1]

Akasaka T., 2002, Endofullerenes: A New Family of Carbon Clusters

[2]

Akasaka T., 2010, CHEM NANOCARBONS

[3] Essential Factors for Control of the Equilibrium in the Reversible Rearrangement of M3N@Ih-C80 Fulleropyrrolidines: Exohedral Functional Groups versus Endohedral Metal Clusters [J].

Aroua, Safwan ;

Garcia-Borras, Marc ;

Osuna, Silvia ;

Yamakoshi, Yoko .

CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (43) :14032-14039

[4] Prato Reaction of M3N@Ih-C80 (M = Sc, Lu, Y, Gd) with Reversible Isomerization [J].

Aroua, Safwan ;

Yamakoshi, Yoko .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (50) :20242-20245

[5] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE [J].

BECKE, AD .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5648-5652

[6] DENSITY-FUNCTIONAL EXCHANGE-ENERGY APPROXIMATION WITH CORRECT ASYMPTOTIC-BEHAVIOR [J].

BECKE, AD .

PHYSICAL REVIEW A, 1988, 38 (06) :3098-3100

[7] Structure and enhanced reactivity rates of the D5h Sc3N@C80 and Lu3N@ C80 metallofullerene isomers:: The importance of the pyracylene motif [J].

Cai, Ting ;

Xu, Liaosa ;

Anderson, Mark R. ;

Ge, Zhongxin ;

Zuo, Tianming ;

Wang, Xuelei ;

Olmstead, Marilyn M. ;

Balch, Alan L. ;

Gibson, Harry W. ;

Dorn, Harry C. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (26) :8581-8589

[8] A pirouette on a metallofullerene sphere:: Interconversion of isomers of N-tritylpyrrolidino Ih Sc3N@C80 [J].

Cai, Ting ;

Slebodnick, Carla ;

Xu, Liaosa ;

Harich, Kim ;

Glass, Thomas E. ;

Chancellor, Christopher ;

Fettinger, James C. ;

Olmstead, Marilyn M. ;

Balch, Alan L. ;

Gibson, Harry W. ;

Dorn, Harry C. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (19) :6486-6492

[9] Unexpected chemical and electrochemical properties of M3N@C80 (M = Sc, Y, Er) [J].

Cardona, Claudia M. ;

Elliott, Bevan ;

Echegoyen, Luis .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (19) :6480-6485

[10] Chemical, Electrochemical, and Structural Properties of Endohedral Metallofullerenes [J].

Chaur, Manuel N. ;

Melin, Frederic ;

Ortiz, Angy L. ;

Echegoyen, Luis .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (41) :7514-7538

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