Aromatic Borataheterocycles: Surrogates for Cyclopentadienyl in Transition-Metal Complexes

被引：81

作者：

Ashe, Arthur J., III ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

ORGANOMETALLICS | 2009年 / 28卷 / 15期

关键词：

OLEFIN POLYMERIZATION CATALYSTS; LEWIS-ACID COMPLEX; B-N; COORDINATION CHEMISTRY; PI-COMPLEXES; TRICARBONYLCHROMIUM COMPLEXES; HETEROAROMATIC-COMPOUNDS; STABILIZED CARBANIONS; 5-MEMBERED RING; C-C;

D O I：

10.1021/om900308e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review, describes the syntheses and coordination chemistry of selected unsaturated borataheterocycles, These compounds are formally derived from common heteroaromatic rings by the isoelectronic substitution of an anionic BH- group for a neutral CH group. Specifically included are the five-membered rings 1,2- and 1,3-thiaborolyls, derived from thiophene, 1,2-oxaborolyl. derived from furan, and 1,2-azaborolyl, derived from pyrrole. Also included is the six-membered ring 1,2-azaboratabenzene, derived from pyridine. These anionic rings can serve is surrogates for cyclopentadienyl in organometallic compounds.

引用

页码：4236 / 4248

页数：13

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