Structural/bonding insights from new geometrical varieties of two Pt-Au carbonyl/phosphine clusters, [Pt3(AuPPh3)5(μ2-CO)2L3]+ (L3 = (CO)2PPh3) and [(μ6-Au){Pt3(μ2-CO)3L4}2]+ (L = PMe3)

被引：7

作者：

de Silva, Namal ^{[1
]}

Laufenberg, Jeffrey W. ^{[1
]}

Dahl, Lawrence F. ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 42期

关键词：

D O I：

10.1039/b609380a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Structural/bonding considerations of two new Pt-Au clusters, [Pt-3(AuPPh3)(5)(mu(2)-CO)(2)(CO)(2)PPh3](+) (1) and [(mu(6)-Au){Pt-3(mu(2)-CO)(3)(PMe3)(4)}(2)](+) (2) isolated (as chloride salts), revealed: (i) that the heretofore unknown 20-electron Pt-centered Pt2Au5 icosahedral cage fragment (five missing vertices) of 1 is best viewed as a 44-electron triangular Pt-3 adduct of a nearly planar 39-electron [Pt-3(mu(2)-CO)L-2(3)](+) (L-3 = (CO)(2)PPh3) and five one-electron donating AuPPh3 ligands; and (ii) that the geometrically distorted trimethylphosphine "full" Pt3AuPt3 sandwich of 2 is the first example of two nucleophilic 44-electron triangular Pt-3(mu(2)-CO)(3)L-4 (3 : 3 : 4) units (L = PMe3) which asymmetrically encapsulate a central electrophilic Au(I).

引用

页码：4437 / 4439

页数：3

共 50 条

[31] Pentabenzylcyclopentadienyl molybdenum and tungsten hydrides: Syntheses, structures and electrochemistry of [MHCpBz(CO)2(L)] (L = CO, PMe3, PPh3)
Antunes, M. Augusta
Namorado, Sonia
de Azevedo, Cristina G.
Lemos, M. Amelia
Duarte, M. Teresa
Ascenso, Jose R.
Martins, Ana M.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (09) : 1328 - 1336
[32] SYNTHESIS OF GROUP-1B SANDWICH CLUSTER COMPOUNDS WITH [PT3(MU-CO)3(PPH3)3] AND THE STRUCTURAL CHARACTERIZATION OF [M(PT3(MU-CO)3(PPH3)3)2]PF6 (M = AU OR CU) BY SINGLE-CRYSTAL X-RAY TECHNIQUES
HALLAM, MF
MINGOS, DMP
ADATIA, T
MCPARTLIN, M
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (02): : 335 - 340
[33] Characterization and catalysis of a SiO2-supported [Au6Pt] cluster [(AuPPh3)(6)Pt(PPh3)](2+)/SiO2
Yuan, YZ
Asakura, K
Wan, HL
Tsai, KR
Iwasawa, Y
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 122 (2-3) : 147 - 157
[34] New research of reaction behaviour of triorganylcyclotriphosphines.: The crystal structures of [(PPh3)2,Pt(P,tBu)3], [(PPh3)2Pd(P,tBu)2], [(CO)4Cr{(P,iPr)3}2], [RhCl(PPh3)(P,tBu)3], [(NiCO)6(μ2-Co)3{(P,tBu)2}2], and [(CpFeCO)2(μ2-CO)(μ-PH,tBu)]+.[FeCl3(thf)]-
Fenske, D
Schottmuller, H
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (03): : 443 - 451
[35] NaY超笼内[Pt3（CO）3（μ2-CO）2]_n2-（n=3,4）簇合物的合成、表征及其催化CO+NO的反应性能
李光进
郭燮贤
藤本
俊幸
福冈淳
市川胜
催化学报, 1993, (05) : 367 - 372
[36] The coordinatively unsaturated cluster cations [Pt3{M(CO)3)(ae-Ph2PCH2PPh2)3 ]+$ / (M = Re, Mn)
J Organomet Chem, 1-2 (01):
[37] THEORETICAL STUDY OF COMPLEXES OF THE TYPE [Pt3(M-L)3(L′)3]-X (L=CO,SO2,CNH; L′=PH3,CNH; X=Tl+, Hg0, MPH3+ (M = Cu, Au, Ag))
Mendizabal, Fernando
Donoso, Daniela
Salazar, Richard
JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2013, 58 (01): : 1562 - 1570
[38] Multiple ligand transfer reaction between [CpRu(L)(AN)2][PF6] (L = AN, CO, P(OMe)3; AN = acetonitrile) and CpFe(CO)L′X (L′ = CO, PMe3, PMe2Ph, PMePh2, PPh3, P(OPh)3; X = Cl, Br, I)
Katayama, T
Onitsuka, K
Takahashi, S
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 610 (1-2) : 31 - 37
[39] Synthesis and Structural/Theoretical (DFT) Analysis of the Geometrically Unprecedented Au–Pt Cluster, Pt7(μ2-CO)8(PPh3)4(μ4-AuPPh3)2: Structure-to-Synthesis Appraisal Concerning Its Formation
Sergei A. Ivanov
Namal de Silva
Michael A. Kozee
Rita V. Nichiporuk
Lawrence F. Dahl
Journal of Cluster Science, 2004, 15 : 233 - 261
[40] NEW TRANSITION-METAL GOLD CLUSTERS - SYNTHESIS AND CHARACTERIZATION OF THE TUNGSTEN GOLD CLUSTERS [W(CO)4(AUPPH3)5](PF6), [W(CO)3(AUPPH3)7](PF6), AND [W(CO)4(AUPPH3)6](NO3)2, CRYSTAL-STRUCTURES OF [W(CO)4(AUPPH3)5](PF6).CH2CL2 AND [W(CO)3(AUPPH3)7](PF6)
KAPPEN, TGMM
VANDENBROEK, ACM
SCHLEBOS, PPJ
BOUR, JJ
BOSMAN, WP
SMITS, JMM
BEURSKENS, PT
STEGGERDA, JJ
INORGANIC CHEMISTRY, 1992, 31 (20) : 4075 - 4080

← 1 2 3 4 5 →