Properties of BaTiO3 synthesized from barium titanyl oxalate

被引：22

作者：

Kim, Jong-Hyun ^{[1
]}

Jung, Won-Sik ^{[1
]}

Kim, Hyun-Tae ^{[1
]}

Yoon, Dang-Hyok ^{[1
]}

机构：

[1] Yeungnam Univ, Sch Mat Sci & Engn, Kyongsan 712749, South Korea

来源：

CERAMICS INTERNATIONAL | 2009年 / 35卷 / 06期

关键词：

Firing; Dielectric properties; BaTiO3 and titanates; Capacitors; PARTICLE-SIZE; POWDER; TETRAGONALITY; DEPENDENCE; TRANSITION;

D O I：

10.1016/j.ceramint.2009.01.006

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

In order to enhance the tetragonality of BaTiO3 derived from barium titanyl oxalate (BTO), various treatments were carried out by considering the thermal decomposition mechanism of BTO in air. A multi-step heat treatment process and the addition of carbon black, as a particle growth inhibitor, were effective in increasing the tetragonality, whilst maintaining a particle size smaller than 200 nm. The synthesized BaTiO3 powder with a mean particle size of 177 urn showed a tetragonality and K-factor of 1.0064 and approximately 3, respectively. (C) 2009 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

引用

页码：2337 / 2342

页数：6

共 17 条

[1] Effects of bovine serum albumin on the low temperature synthesis of barium titanate microparticles via a solid state route
Ando, C
Kishi, H
Oguchi, H
Senna, M
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2006, 89 (05) : 1709 - 1712
[2] Ishikawa K, 1998, J KOREAN PHYS SOC, V32, pS56
[3] SPACE CHARGE LAYER NEAR THE SURFACE OF A FERROELECTRIC
KANZIG, W
[J]. PHYSICAL REVIEW, 1955, 98 (02): : 549 - 550
[4] Solvothermally synthesized tetragonal barium titanate powders using H2O/EtOH solvent
Kwon, SG
Park, BH
Choi, K
Choi, ES
Nam, S
Kim, JW
Kim, JH
[J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2006, 26 (08) : 1401 - 1404
[5] Effects of heat treatment and particle size on the tetragonality of nano-sized barium titanate powder
Kwon, Sung-Wook
Yoon, Dang-Hyok
[J]. CERAMICS INTERNATIONAL, 2007, 33 (07) : 1357 - 1362
[6] Synthesis of BaTiO3 powder from barium titanyl oxalate (BTO) precursor employing microwave heating technique
Malghe, YS
Gurjar, AV
Dharwadkar, SR
[J]. BULLETIN OF MATERIALS SCIENCE, 2004, 27 (03) : 217 - 220
[7] THE ELECTRIC AND OPTICAL BEHAVIOR OF BATIO3 SINGLE-DOMAIN CRYSTALS
MERZ, WJ
[J]. PHYSICAL REVIEW, 1949, 76 (08): : 1221 - 1225
[8] MURTHY HSG, 1975, J INORG NUCL CHEM, V37, P1875
[9] NIEPCE JC, 1989, SURF INTERFACES, P512
[10] Solid-state synthesis of nano-sized BaTiO3 powder with high tetragonality
Ryu, Sung-Soo
Yoon, Dang-Hyok
[J]. JOURNAL OF MATERIALS SCIENCE, 2007, 42 (17) : 7093 - 7099

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