Unique photoreactivity of mercury(II) 5,10,15,20-tetrakis (4-sulfonatophenyl)porphyrin

被引：28

作者：

Horváth, O

Valicsek, Z

Vogler, A

机构：

[1] Univ Veszprem, Dept Gen & Inorgan Chem, H-8201 Veszprem, Hungary

[2] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 07期

基金：

匈牙利科学研究基金会;

关键词：

photophysics; photochemistry; charge transfer; dissociation; metalloporphyrin; mercury;

D O I：

10.1016/j.inoche.2004.05.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Deviating from coplanar metalloporphyrins, the photochemistry of the kinetically labile, sitting-atop mercury(II) 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin complex is characterized by irreversible porphyrin ligand to metal charge transfer and reversible dissociation. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：854 / 857

页数：4

共 19 条

[1]

ADEYEMO AO, 1984, INORG CHIM ACTA, V83, P41, DOI DOI 10.1016/S0020-1693(00)82504-9

[2] Kinetics of the reactions of divalent copper, zinc, cobalt, and nickel with a deformed water soluble centrally monoprotic porphyrin [J].