Aluminium dodecyl sulfate trihydrate [Al(DS)3]•3H2O: An efficient Lewis acid-surfactant-combined catalyst for synthesis of 1,8-dioxo-octahydroxanthens and 1,8-dioxo-decahydroacridines

被引：0
作者：
Hasaninejad, A. [1 ]
Yousefy, T. [2 ]
Firoozi, S. [1 ]
机构：
[1] Persian Gulf Univ, Fac Sci, Dept Chem, Bushehr 75169, Iran
[2] Islamic Azad Univ, Dept Chem, Gachsaran, Iran
来源：
IRANIAN JOURNAL OF SCIENCE AND TECHNOLOGY TRANSACTION A-SCIENCE | 2015年 / 39卷 / A2期
关键词：
Aluminium dodecyl sulfate trihydrate; Lewis acid; Lewis acid surfactant catalyst; Xanthenes; 1,8-Dioxo-octahydroxanthens; Acridinediones; 1,8-Dioxo-decahydroacridines; multi component reactions; green chemistry; P-DODECYLBENEZENESULFONIC ACID; SOLVENT-FREE CONDITIONS; ONE-POT SYNTHESIS; AQUEOUS-MEDIA; HIGHLY EFFICIENT; ROOM-TEMPERATURE; CLEAN SYNTHESIS; IONIC LIQUID; LASER-DYES; ACRIDINEDIONE DERIVATIVES;
D O I：
暂无
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
An efficient synthesis of 1, 8-dioxo-octahydroxanthens and 1, 8-dioxo-decahydroacridines from the reaction of 5,5-dimethy1-1,3-cyclohexanedione (dimedone) with aromatic aldehydes bearing electron -donating or withdrawing substituents either in the presence or absence of primary amines has been described in a single pot using a catalytic amounts of aluminum tris (dodecyl sulfate) trihydrate [Al(DS)3.3H(2)O] as a Lewis acid -surfactant combined catalyst. Both reactions occurred at 80 degrees C. 1, 8-dioxo-octahydroxanthens has been synthesized under solvent -free conditions and water is used as a green solvent for the synthesis of 1, 8-dioxo-decahydroacridines. This methodology offers several advantages such as very simple work -up procedure, short reaction times, and mild reaction conditions.
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页码：129 / 140
页数：12
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