Direct synthesis of acetylene from methane by direct current pulse discharge

被引:64
|
作者
Kado, S [1 ]
Sekine, Y [1 ]
Fujimoto, K [1 ]
机构
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
关键词
D O I
10.1039/a906914c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In non-catalytic direct conversion of methane to acetylene by using direct current pulse discharge under conditions of ambient temperature and atmospheric pressure, the selectivity of acetylene from methane was > 95% at methane conversion ranging from 16 to 52%; coexisting oxygen was very effective in removing deposited carbon and stabilized the state of discharge.
引用
收藏
页码:2485 / 2486
页数:2
相关论文
共 50 条
  • [1] Low temperature reforming of methane to synthesis gas with direct current pulse discharge method
    Kado, S
    Urasaki, K
    Sekine, Y
    Fujimoto, K
    CHEMICAL COMMUNICATIONS, 2001, (05) : 415 - 416
  • [2] ACETYLENE REACTION WITH HYDROGEN IN A GLOW-DISCHARGE OF DIRECT-CURRENT
    BEBESHKO, GI
    EREMIN, EN
    ZHURNAL FIZICHESKOI KHIMII, 1974, 48 (03): : 611 - 612
  • [3] Direct current cathodic glow discharge polymerization of methane and butane
    Miyama, M
    Yasuda, HK
    JOURNAL OF APPLIED POLYMER SCIENCE, 1998, 70 (02) : 237 - 245
  • [4] DIRECT SYNTHESIS FULVENE OF ACETYLENE
    CHUKHADZHYAN, GA
    ABRAMYAN, ZI
    TONYAN, GM
    ARMYANSKII KHIMICHESKII ZHURNAL, 1975, 28 (11): : 942 - 943
  • [5] Methane reforming to valuable products by an atmospheric pressure direct current discharge
    SriBala, Gorugantu
    Michiels, Dries
    Leys, Christophe
    Van Geem, Kevin M.
    Marin, Guy B.
    Nikiforov, Anton
    JOURNAL OF CLEANER PRODUCTION, 2019, 209 : 655 - 664
  • [6] Acetylene polymerization in plasma of direct current
    Alvarez, B.
    Sarmiento-Santos, A.
    Vera-Lopez, E.
    5TH INTERNATIONAL MEETING FOR RESEARCHERS IN MATERIALS AND PLASMA TECHNOLOGY (5TH IMRMPT), 2019, 1386
  • [8] Direct synthesis of oxygenates from water and methane via dielectric-barrier discharge
    Wang, BW
    Xu, GH
    CHINESE CHEMICAL LETTERS, 2004, 15 (07) : 779 - 780
  • [9] Polymer synthesis from 1-aminonaphthalene in direct-current discharge
    I. V. Semenov
    A. B. Gil’man
    M. Yu. Yablokov
    N. M. Surin
    A. N. Shchegolikhin
    N. A. Shmakova
    A. A. Kuznetsov
    High Energy Chemistry, 2011, 45 : 157 - 161
  • [10] Polymer Synthesis from 1-Aminonaphthalene in Direct-Current Discharge
    Semenov, I. V.
    Gil'man, A. B.
    Yablokov, M. Yu.
    Surin, N. M.
    Shchegolikhin, A. N.
    Shmakova, N. A.
    Kuznetsov, A. A.
    HIGH ENERGY CHEMISTRY, 2011, 45 (02) : 157 - 161