On the preparation of tetramethylammonium trifluoromethylbistrifluoromethylnitroxyliodate(I) (CH3)(4)N+(CF3)2NOICF(3)(-) and the reaction of tetramethylammonium bistrifluoromethylnitrate (CH3)(4)N+(CF3)(2)NO- with Cl-2 and ClONO2

被引：1
|
作者：
Minkwitz, R
Jakob, J
机构：
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1997年 / 623卷 / 04期
关键词：
tetramethylammonium bistrifluoromethylnitrate; tetramethylammonium trinuoromethylbistrifluoromethylnitroxyliodate(I); bistrifluoromethylnitroxyde; vibrational spectra; F-19; C-13; NMR;
D O I：
10.1002/zaac.19976230196
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The preparation of (CF3)(2)NO- as tetramethylammoniumsalt and its addition reaction with CF3I are described. The formed Tetramethylammonium trifluoromethylbistrifluoromethylnitroxyliodate(I) (CH3)(4)N+(CF3)(2)NOICF3- is characterized by its spectra and the reaction with CF3OCl. In addition we present our approach to the preparation of (CF3)(2)NOCl by the reaction of (CH3)(4)N+(CF3)(2)NO- With Cl-2 and ClONO2. The thermolabile compounds have been characterized by i. r., Raman, F-19 and C-13 NMR spectra.
引用
收藏
页码：613 / 618
页数：6
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