Fabrication of Pt/Pd Nanoparticles/Polyoxometalate/Ionic Liquid Nanohybrid for Electrocatalytic Oxidation of Methanol

被引:45
作者
Medetalibeyoglu, Hilal [1 ]
Manap, Sevda [1 ]
Yokus, Ozlem Aktas [2 ]
Beytur, Murat [1 ]
Kardas, Faruk [3 ]
Akyildirim, Onur [4 ]
Ozkan, Vildan [5 ]
Yuksek, Haydar [1 ]
Yola, Mehmet Lutfi [6 ]
Atar, Necip [7 ]
机构
[1] Kafkas Univ, Fac Sci & Letters, Dept Chem, Kars, Turkey
[2] Kafkas Univ, Dept Sci Educ, Fac Educ, Kars, Turkey
[3] Erzincan Univ, Dept Sci Educ, Fac Educ, Erzincan, Turkey
[4] Kafkas Univ, Dept Chem Engn, Fac Engn & Architecture, Kars, Turkey
[5] Iskenderun Tech Univ, Fac Engn & Nat Sci, Dept Petr & Nat Gas, Antakya, Turkey
[6] Iskenderun Tech Univ, Fac Engn & Nat Sci, Dept Biomed Engn, Antakya, Turkey
[7] Pamukkale Univ, Dept Chem Engn, Fac Engn, Denizli, Turkey
关键词
SENSITIVE VOLTAMMETRIC SENSOR; GRAPHENE OXIDE; BIMETALLIC NANOPARTICLES; PASTE ELECTRODE; FUEL-CELLS; POLYOXOMETALATE; ACID;
D O I
10.1149/2.1041805jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Fuel cells have important applications in recent decades due to high-energy demands, fossil fuel depletions, and environmental pollution throughout world. Pt/Pd nanoparticles/polyoxometalate/ionic liquid (ILs) nanohybrid synthesized for the first time and characterized by transmission electron microscope, scanning electron microscope, X-ray photo electron spectroscopy, energy-dispersive X-ray spectroscopy and X-ray diffraction method. A cost-effective catalyst has been developed on Pt/Pd nanoparticles/polyoxometalate/ionic liquid nanohybrid. The developed catalyst based on bimetallic nanoparticle demonstrates effective methanol oxidation in comparison with catalysts on monometallic nanoparticle and polyoxometalate/ionic liquid nanohybrid. (C) 2018 The Electrochemical Society.
引用
收藏
页码:F338 / F341
页数:4
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