IMPROVED SURFACE ENHANCED RAMAN SCATTERING FOR NANOSTRUCTURED SILVER ON POROUS SILICON FOR ULTRASENSITIVE DETERMINATION OF 2,4,6-TRINITROTOLUENE

被引:29
|
作者
Lai, Yuming [1 ,3 ]
Wang, Jing [1 ]
He, Tao [1 ]
Sun, Shuqing [2 ]
机构
[1] Natl Ctr Nanosci & Technol, Lab Nanodevice, Beijing, Peoples R China
[2] Tsinghua Univ, Grad Sch Shenzhen, Shenzhen Key Lab Minimally Invas Med Technol, Lab Opt Imaging & Sensing, Shenzhen 518055, Peoples R China
[3] Chinese Acad Sci, Grad Univ, Beijing, Peoples R China
关键词
Porous Si; SERS; Surface enhanced Raman scattering; TNT; METAL-DEPOSITION; SERS; TNT; NANOPARTICLES;
D O I
10.1080/00032719.2013.850089
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Label-free and low-cost surface-enhanced Raman scattering-active substrates of silver nanostructures on porous silicon have been synthesized. The morphology and spectroscopic properties were investigated as a function of concentration and immersion time. The enhancement factor of optimized silver-porous silicon substrate was estimated to be 2.18x10(8) by the use of p-thiocresol as a Raman probe. The optimized substrate was used to determine 50pg of 2,4,6-trinitrotoluene. These results demonstrate that the prepared silver-porous silicon substrates are promising for the ultra-sensitive determination of organic molecules.
引用
收藏
页码:833 / 842
页数:10
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