Targeted Self-Healing by Magnetically Guiding Microcapsules

被引:22
作者
Crall, Matthew D. [1 ]
Keller, Michael W. [1 ]
机构
[1] Univ Tulsa, Dept Mech Engn, 800 S Tucker Dr, Tulsa, OK 74104 USA
基金
美国国家科学基金会;
关键词
self-healing magnetic nanoparticles; microencapsulation; polymeric materials; targeted location; guided placement; IRON-OXIDE NANOPARTICLES; GAMMA-FE2O3; NANOPARTICLES; FE3O4; POLYMERIC MATERIALS; DRUG-DELIVERY; COMPOSITES; COATINGS; MICROENCAPSULATION; DICYCLOPENTADIENE; PERFORMANCE;
D O I
10.1021/acsami.7b00459
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Magnetically guided microcapsules are used to achieve self-healing with 1/10th of the healing components required using traditional self-healing approaches. Microcapsules are rendered responsive to magnetic fields by suspending magnetic nanoparticles in the core material. The nanoparticles are surface-modified to enable urea formaldehyde encapsulation within a phenyl acetate core. Magnetic fields are used to guide the microcapsules to the expected fracture location in tapered double-cantilever beam (TDCB) epoxy specimens. This guiding method achieves an order of magnitude increase in local microcapsule concentration over controls, resulting in successful self-healing at microcapsule concentrations as low as 0.025 wt %. Additionally, the observed healing is both more consistent and significantly higher than that of control specimens, remaining relatively constant across all weight percentages tested.
引用
收藏
页码:6504 / 6511
页数:8
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