Targeted Self-Healing by Magnetically Guiding Microcapsules

被引:22
作者
Crall, Matthew D. [1 ]
Keller, Michael W. [1 ]
机构
[1] Univ Tulsa, Dept Mech Engn, 800 S Tucker Dr, Tulsa, OK 74104 USA
基金
美国国家科学基金会;
关键词
self-healing magnetic nanoparticles; microencapsulation; polymeric materials; targeted location; guided placement; IRON-OXIDE NANOPARTICLES; GAMMA-FE2O3; NANOPARTICLES; FE3O4; POLYMERIC MATERIALS; DRUG-DELIVERY; COMPOSITES; COATINGS; MICROENCAPSULATION; DICYCLOPENTADIENE; PERFORMANCE;
D O I
10.1021/acsami.7b00459
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Magnetically guided microcapsules are used to achieve self-healing with 1/10th of the healing components required using traditional self-healing approaches. Microcapsules are rendered responsive to magnetic fields by suspending magnetic nanoparticles in the core material. The nanoparticles are surface-modified to enable urea formaldehyde encapsulation within a phenyl acetate core. Magnetic fields are used to guide the microcapsules to the expected fracture location in tapered double-cantilever beam (TDCB) epoxy specimens. This guiding method achieves an order of magnitude increase in local microcapsule concentration over controls, resulting in successful self-healing at microcapsule concentrations as low as 0.025 wt %. Additionally, the observed healing is both more consistent and significantly higher than that of control specimens, remaining relatively constant across all weight percentages tested.
引用
收藏
页码:6504 / 6511
页数:8
相关论文
共 46 条
[1]   Synthesis of maghemite (γ-Fe2O3) nanoparticles by thermal-decomposition of magnetite (Fe3O4) nanoparticles [J].
Aliahmad, M. ;
Moghaddam, N. Nasiri .
MATERIALS SCIENCE-POLAND, 2013, 31 (02) :264-268
[2]   Particles as surfactants - similarities and differences [J].
Binks, BP .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2002, 7 (1-2) :21-41
[3]   Robust synthesis of epoxy resin-filled microcapsules for application to self-healing materials [J].
Bolimowski, Patryk A. ;
Bond, Ian P. ;
Wass, Duncan F. .
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2016, 374 (2061)
[4]   Magnetic order in γ-Fe2O3 nanoparticles:: a XMCD study [J].
Brice-Profeta, S ;
Arrio, MA ;
Tronc, E ;
Menguy, N ;
Letard, I ;
Moulin, CCD ;
Noguès, M ;
Chanéac, C ;
Jolivet, JP ;
Sainctavit, P .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2005, 288 :354-365
[5]   Use of the tapered double-cantilever beam geometry for fracture toughness measurements and its application to the quantification of self-healing [J].
Brown, E. N. .
JOURNAL OF STRAIN ANALYSIS FOR ENGINEERING DESIGN, 2011, 46 (03) :167-186
[6]   Microcapsule induced toughening in a self-healing polymer composite [J].
Brown, EN ;
White, SR ;
Sottos, NR .
JOURNAL OF MATERIALS SCIENCE, 2004, 39 (05) :1703-1710
[7]   In situ poly(urea-formaldehyde) microencapsulation of dicyclopentadiene [J].
Brown, EN ;
Kessler, MR ;
Sottos, NR ;
White, SR .
JOURNAL OF MICROENCAPSULATION, 2003, 20 (06) :719-730
[8]   Full recovery of fracture toughness using a nontoxic solvent-based self-healing system [J].
Caruso, Mary M. ;
Blaiszik, Benjamin J. ;
White, Scott R. ;
Sottos, Nancy R. ;
Moore, Jeffrey S. .
ADVANCED FUNCTIONAL MATERIALS, 2008, 18 (13) :1898-1904
[9]   Solvent-promoted self-healing epoxy materials [J].
Caruso, Mary M. ;
Delafuente, David A. ;
Ho, Victor ;
Sottos, Nancy R. ;
Moore, Jeffrey S. ;
White, Scott R. .
MACROMOLECULES, 2007, 40 (25) :8830-8832
[10]   Robust, Double-Walled Microcapsules for Self-Healing Polymeric Materials [J].
Caruso, Mary M. ;
Blaiszik, Benjamin J. ;
Jin, Henghua ;
Schelkopf, Stuart R. ;
Stradley, Dylan S. ;
Sottos, Nancy R. ;
White, Scott R. ;
Moore, Jeffrey S. .
ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (04) :1195-1199