Analysis of the chemical processes occurring in the system PbSO4-ZnS

被引:8
作者
Malinowski, C
Malinowska, K
Malecki, S
机构
[1] Faculty of Non-Ferrous Metals, Academy of Mining and Metallurgy, 30-059 Krakow
关键词
decomposition; lead sulfate; oxidation; reaction in the state phase; zinc sulfide;
D O I
10.1016/0040-6031(95)02699-1
中图分类号
O414.1 [热力学];
学科分类号
摘要
Research carried out on the interactions between PbSO4 and ZnS, using mixtures with variable molar ratios of PbSO4:ZnS, showed that the process starts at 803 K. It was found that a few reactions occur at the same time, including transformation of zinc sulfide into its oxide and PbS formation; the secondary lead sulfate containing the sulfur from ZnS also appears. The PbS is derived primarily from PbSO4, and some of it contains the sulfur from ZnS.
引用
收藏
页码:117 / 130
页数:14
相关论文
共 20 条
[11]  
MALINOWSKI C, 1982, C NEW SCI TECHN ACH, P104
[12]  
MALINOWSKI C, 1987, ARCH METALL, V32, P203
[13]  
MALINOWSKI C, 1987, THERMOCHIM ACTA, P329
[14]  
MALINOWSKI C, 1984, ARCH HUTN, V23, P53
[15]  
MALINOWSKI C, 1987, ZN AGH METALURGIA OD, V109, P113
[16]  
MALINOWSKI C, 1992, ZN AGH METALURGIA OD, V141, P7
[17]  
MALINOWSKI C, 1987, 19 OKT SAV RUD MET T, P152
[18]  
OSTROFF AG, 1956, J INORG NUCL CHEM, V8, P45
[19]  
PONOMAREV VD, 1975, IZBRANNYE T KHIMIA T, P151
[20]  
SKACHKOV BJ, 1958, TSVETN METALL, V11, P25