Significant developments in rare-earth-containing polyoxometalate chemistry: synthetic strategies, structural diversities and correlative properties

被引：73

作者：

Ma, Xing ^{[1
]}

Yang, Wen ^{[1
]}

Chen, Lijuan ^{[1
]}

Zhao, Junwei ^{[1
]}

机构：

[1] Henan Univ, Coll Chem & Chem Engn, Inst Mol & Crystal Engn, Henan Key Lab Polyoxometalate Chem, Kaifeng 475004, Henan, Peoples R China

来源：

CRYSTENGCOMM | 2015年 / 17卷 / 43期

基金：

中国国家自然科学基金;

关键词：

ORGANIC-COMPLEXES CORRELATION; CRYSTAL-STRUCTURE; KEGGIN-TYPE; LANTHANIDE COMPLEXES; BUILDING-BLOCKS; METAL-OXIDE; HETEROPOLYTUNGSTATE COMPLEXES; DAWSON POLYOXOTUNGSTATE; MAGNETIC-PROPERTIES; AQUEOUS-SOLUTION;

D O I：

10.1039/c5ce01240f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Owing to their unique and abundant structures and potential multi-fold applications in various fields such as luminescence, magnetism, catalysis, etc., rare-earth-containing polyoxometalates (RECPs) play an important role in the development of polyoxometalate chemistry. In this article, the major progress in RECPs made in the past decade involving synthetic strategies, structural characteristics and some significant properties related to optics, catalysis and magnetism is highlighted and discussed. The final section is committed to looking forward to some future perspectives in this field and providing some personal insights or viewpoints for the ongoing trends in the future.

引用

页码：8175 / 8197

页数：23

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