Optical and electrical properties of nickel oxide thin films synthesized by sol-gel spin coating

被引:75
作者
Jlassi, M. [1 ]
Sta, I. [1 ]
Hajji, M. [1 ,2 ]
Ezzaouia, H. [1 ]
机构
[1] Ctr Rech & Technol Energie, Lab Photovolta, Hammam Lif 2050, Tunisia
[2] Univ Sfax, Inst Super Elect & Commun Sfax, Sfax, Tunisia
关键词
Thin films; Nickel oxide; Sol-gel; Spin coating; Structural analysis; Electrical and optical properties; SUBSTRATE; CONSTANTS; LAYER;
D O I
10.1016/j.mssp.2014.01.018
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Nickel oxide thin films were prepared by the sol-gel technique combined with spin coating onto glass substrates. The as-deposited films were pre-heated at 275 degrees C for 15 min and then annealed in air at different temperatures. The effects of the annealing temperature on the structural and optical properties of the films are studied. The results show that 600 degrees C is the optimum annealing temperature for preparation of NiO films with p-type conductivity and high optical transparency. Then, by using these optimized deposition parameters, NiO thin films of various thicknesses were deposited at the same experimental conditions and annealed under different atmospheres. Surface morphology of the films was investigated by atomic force microscopy. The surface morphology of the films varies with the annealing atmosphere. Optical transmission was studied by UV-vis spectrophotometer. The transmittance of films decreased as the thickness of films increased. The electrical resistivity, obtained by four-point probe measurements, was improved when NiO layers were annealed in N-2 atmosphere at 600 degrees C. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7 / 13
页数:7
相关论文
共 18 条
[1]   Electrical and optical properties of narrow-band materials [J].
Adler, David ;
Feinleib, Julius .
PHYSICAL REVIEW B-SOLID STATE, 1970, 2 (08) :3112-3134
[2]   Structure and optical properties of nanocrystalline NiO thin film synthesized by sol-gel spin-coating method [J].
Al-Ghamdi, A. A. ;
Mahmoud, Waleed E. ;
Yaghmour, S. J. ;
Al-Marzouki, F. M. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 486 (1-2) :9-13
[3]   Electrochromic materials and devices:: Brief survey and new data on optical absorption in tungsten oxide and nickel oxide films [J].
Avendaño, E ;
Berggren, L ;
Niklasson, GA ;
Granqvist, CG ;
Azens, A .
THIN SOLID FILMS, 2006, 496 (01) :30-36
[4]  
Balu AR., 2012, J. Electron. Devices, V13, P920
[5]  
Cullity B. D., ELEMENTS XRAY DIFFRA
[6]  
Hwang S. T., 2010, T ELECT ELECT MAT, V2, P81
[7]   p-Type semiconducting nickel oxide as an efficiency-enhancing anode interfacial layer in polymer bulk-heterojunction solar cells [J].
Irwin, Michael D. ;
Buchholz, Bruce ;
Hains, Alexander W. ;
Chang, Robert P. H. ;
Marks, Tobin J. .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2008, 105 (08) :2783-2787
[8]  
Jarzebski Z.M., 1973, OXIDE SEMICONDUCTORS, p[150, 184]
[9]   Vertically aligned and interconnected nickel oxide nanowalls fabricated by hydrothermal route [J].
Kumari, L. ;
Li, W. Z. ;
Vannoy, C. H. ;
Leblanc, R. M. ;
Wang, D. Z. .
CRYSTAL RESEARCH AND TECHNOLOGY, 2009, 44 (05) :495-499
[10]  
Lee KD, 2004, J KOREAN PHYS SOC, V45, P447