Pd-catalyzed aerobic direct olefination of polyfiuoroarenes

被引：11
作者：
He, Chun-Yang [1 ]
Qing, Feng-Ling [1 ,2 ]
Zhang, Xingang [2 ]
机构：
[1] Donghua Univ, Coll Chem Chem Engn & Biotechnol, Shanghai 201620, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China
来源：
TETRAHEDRON LETTERS | 2014年 / 55卷 / 18期
基金：
中国国家自然科学基金;
关键词：
C-H functionalization; Olefination; Oxygen; Palladium; Polyfluoroarenes; ELECTRON-DEFICIENT POLYFLUOROARENES; C-H BOND; DIRECT ARYLATION; FACILE ACCESS; ALKENYLATION; ALLYLATION; ACTIVATION; FLUORINE; ARENES; FUNCTIONALIZATION;
D O I：
10.1016/j.tetlet.2014.03.096
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first example of Pd-catalyzed aerobic direct olefination of polyfluoroarenes has been developed. The reaction makes use of molecular O-2 as terminal oxidant, and provides a cost-efficient and environmentally benign access to polyfluoroarene-alkene structures that are of interest in life and material sciences. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2962 / 2964
页数：3
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