High selectivity of TaSiBEA zeolite catalysts in 1,3-butadiene production from ethanol and acetaldehyde mixture

被引：71

作者：

Kyriienko, Pavlo I. ^{[1
]}

Larina, Olga V. ^{[1
]}

Soloviev, Sergiy O. ^{[1
]}

Orlyk, Svitlana M. ^{[1
]}

Dzwigaj, Stanislaw ^{[2
,3
]}

机构：

[1] NAS Ukraine, LV Pisarzhevsky Inst Phys Chem, 31 Prosp Nauky, UA-03028 Kiev, Ukraine

[2] Univ Paris 06, Sorbonne Univ, UMR 7197, Lab React Surface, F-75005 Paris, France

[3] CNRS, UMR 7197, Lab React Surface, F-75005 Paris, France

来源：

CATALYSIS COMMUNICATIONS | 2016年 / 77卷

关键词：

Tantalum; BEA; Ethanol; 1,3-Butadiene; Catalysis; ONE-STEP; CONVERSION; BUTADIENE; SITES; FRAMEWORK; PYRROLE; FTIR; BETA;

D O I：

10.1016/j.catcom.2016.01.023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New tantalum-silica based zeolite catalysts (TaSiBEA) were applied in this work for 1,3-butadiene production from ethanol. Tantalum incorporation into vacant T-atom sites of the SiBEA zeolites framework as mononuclear Ta(V) allowed preparing highly selective catalysts for ethanol/acetaldehyde mixture conversion into 1,3-butadiene, with selectivity to 1,3-butadiene of 80-90% at total conversion of the mixture of 45-30%. Effect of Ta content on activity of TaSiBEA zeolite catalysts and the ethanol/acetaldehyde molar ratio in selective production of 1,3 butadiene were demonstrated. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：123 / 126

页数：4

共 27 条

[1] Ex Situ and Operando Studies on the Role of Copper in Cu-Promoted SiO2-MgO Catalysts for the Lebedev Ethanol-to-Butadiene Process [J].

Angelici, Carlo ;

Meirer, Florian ;

van der Eerden, Ad M. J. ;

Schaink, Herrick L. ;

Goryachev, Andrey ;

Hofmann, Jan P. ;

Hensen, Emiel J. M. ;

Weckhuysen, Bert M. ;

Bruijnincx, Pieter C. A. .

ACS CATALYSIS, 2015, 5 (10) :6005-6015

[2] Influence of acid-base properties on the Lebedev ethanol-to-butadiene process catalyzed by SiO2-MgO materials [J].

Angelici, Carlo ;

Velthoen, Marjolein E. Z. ;

Weckhuysen, Bert M. ;

Bruijnincx, Pieter C. A. .

CATALYSIS SCIENCE & TECHNOLOGY, 2015, 5 (05) :2869-2879

[3] Chemocatalytic Conversion of Ethanol into Butadiene and Other Bulk Chemicals [J].

Angelici, Carlo ;

Weckhuysen, Bert M. ;

Bruijnincx, Pieter C. A. .

CHEMSUSCHEM, 2013, 6 (09) :1595-1614

[4] KINETIC STUDY ON MECHANISM OF CATALYTIC CONVERSION OF ETHANOL TO BUTADIENE [J].

BHATTACHARYYA, SK ;

SANYAL, SK .

JOURNAL OF CATALYSIS, 1967, 7 (02) :152-+

[5] Butadiene production from bioethanol and acetaldehyde over tantalum oxide-supported ordered mesoporous silica catalysts [J].

Chae, Ho-Jeong ;

Kim, Tae-Wan ;

Moon, Young-Kyun ;

Kim, Han-Kyu ;

Jeong, Kwang-Eun ;

Kim, Chul-Ung ;

Jeong, Soon-Yong .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 150 :596-604

[6] Supported tantalum oxide catalysts: Synthesis, physical characterization, and methanol oxidation chemical probe reaction [J].

Chen, YS ;

Fierro, JLG ;

Tanaka, T ;

Wachs, IE .

JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (22) :5243-5250

[7] On the Chemistry of Ethanol on Basic Oxides: Revising Mechanisms and Intermediates in the Lebedev and Guerbet reactions [J].

Chieregato, Alessandro ;

Ochoa, Juliana Velasquez ;

Bandinelli, Claudia ;

Fornasari, Giuseppe ;

Cavani, Fabrizio ;

Mella, Massimo .

CHEMSUSCHEM, 2015, 8 (02) :377-388

[8] Water Resistant, Catalytically Active Nb and Ta Isolated Lewis Acid Sites, Homogeneously Distributed by Direct Synthesis in a Beta Zeolite [J].

Corma, Avelino ;

Llabres i Xamena, Francesc X. ;

Prestipino, Carmelo ;

Renz, Michael ;

Valencia, Susana .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (26) :11306-11315

[9] BUTADIENE FROM ETHYL ALCOHOL - CATALYSIS IN THE ONE-STEP AND 2-STEP PROCESSES [J].

CORSON, BB ;

JONES, HE ;

WELLING, CE ;

HINCKLEY, JA ;

STAHLY, EE .

INDUSTRIAL AND ENGINEERING CHEMISTRY, 1950, 42 (02) :359-373

[10] Incorporation of Silver Atoms into the Vacant T-Atom Sites of the Framework of SiBEA Zeolite as Mononuclear Ag(I) Evidenced by XRD, FTIR, NMR, DR UV-vis, XPS, and TPR [J].

Dzwigaj, Stanislaw ;

Millot, Yannick ;

Krafft, Jean-Marc ;

Popovych, Nataliia ;

Kyriienko, Pavlo .

JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (24) :12552-12559

← 1 2 3 →