Superstructure manipulation and electronic measurement of monolayers comprising discotic liquid crystals with intrinsic dipole moment using STM/STS

被引:15
作者
Cheng, Kum-Yi [2 ]
Lin, Chih-Hsun [2 ]
Tzeng, Mei-Chun [3 ]
Mahmood, Ayyaz [1 ]
Saeed, Muhammad [1 ]
Chen, Chun-Hsien [2 ]
Ong, Chi Wi [3 ]
Lee, Shern-Long [1 ]
机构
[1] Shenzhen Univ, Inst Adv Study, Shenzhen 518060, Guangdong, Peoples R China
[2] Natl Taiwan Univ, Ctr Emerging Mat & Adv Devices, Dept Chem, Taipei 10617, Taiwan
[3] Natl Sun Yat Sen Univ, Dept Chem, Kaohsiung 80424, Taiwan
关键词
ALKYL CHAIN; INTERFACE; 2D; CONFORMATION; DERIVATIVES; ASSEMBLIES; NETWORKS; AU(111); PACKING;
D O I
10.1039/c8cc04241a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this work, we studied the discotic liquid crystals (DLCs) of dibenzo[a,c]phenazine at the liquid-solid interface using scanning tunnelling microscopy/spectroscopy, by which we show how to tailor the DLC assemblies and in turn their electron-transfer efficiency. This study presents an alternative method for phase control and electronic measurements for DLCs, especially at the microscopic level.
引用
收藏
页码:8048 / 8051
页数:4
相关论文
共 21 条
[1]   Orientation of organic molecules in a monolayer vis-a-vis their molecular orbitals and transport gap [J].
Chakrabarti, Sudipto ;
Dey, Sukumar ;
Pal, Amlan J. .
APPLIED PHYSICS LETTERS, 2011, 99 (05)
[2]   Structural selection of graphene supramolecular assembly oriented by molecular conformation and alkyl chain [J].
Chen, Qing ;
Chen, Ting ;
Pan, Ge-Bo ;
Yan, Hui-Juan ;
Song, We'Guo ;
Wan, Li-Jun ;
Li, Zhong-Tao ;
Wang, Zhao-Hui ;
Shang, Bo ;
Yuan, Lan-Feng ;
Yang, Jin-Long .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2008, 105 (44) :16849-16854
[3]   Snapshotting the Excited-State Planarization of Chemically Locked N,N′-Disubstituted Dihydrodibenzo[a,c]phenazines [J].
Chen, Wei ;
Chen, Chi-Lin ;
Zhang, Zhiyun ;
Chen, Yi-An ;
Chao, Wei-Chih ;
Su, Jianhua ;
Tian, He ;
Chou, Pi-Tai .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (04) :1636-1644
[4]   Monolayer to multilayer nanostructural growth transition in N-type oligothiophenes on Au(111) and implications for organic field-effect transistor performance [J].
Dholakia, Geetha R. ;
Meyyappan, M. ;
Facchetti, Antonio ;
Marks, Tobin J. .
NANO LETTERS, 2006, 6 (11) :2447-2455
[5]   Discotic Liquid Crystals for Opto-Electronic Applications [J].
Kaafarani, Bilal R. .
CHEMISTRY OF MATERIALS, 2011, 23 (03) :378-396
[6]   Solvent induced polymorphism in supramolecular 1,3,5-benzenetribenzoic acid monolayers [J].
Kampschulte, Lorenz ;
Lackinger, Markus ;
Maier, Anne-Kathrin ;
Kishore, Ravuri S. K. ;
Griessl, Stefan ;
Schmittel, Michael ;
Heckl, Wolfgang M. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (22) :10829-10836
[7]   Self-assembly of discotic mesogens in solution and in liquid crystalline phases: Effects of substituent position and hydrogen bonding [J].
Lavigueur, Christine ;
Foster, E. Johan ;
Williams, Vance E. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (35) :11791-11800
[8]   Reversible Local and Global Switching in Multicomponent Supramolecular Networks: Controlled Guest Release and Capture at the Solution/Solid Interface [J].
Lee, Shern-Long ;
Fang, Yuan ;
Velpula, Gangamallaiah ;
Cometto, Fernando R. ;
Lingenfelder, Magali ;
Muellen, Klaus ;
Mali, Kunal S. ;
De Feyter, Steven .
ACS NANO, 2015, 9 (12) :11608-11617
[9]   Efficient screening of 2D molecular polymorphs at the solution-solid interface [J].
Lee, Shern-Long ;
Adisoejoso, Jinne ;
Fang, Yuan ;
Tahara, Kazukuni ;
Tobe, Yoshito ;
Mali, Kunal S. ;
De Feyter, Steven .
NANOSCALE, 2015, 7 (12) :5344-5349
[10]   Biaxial aromatics with face-on/edge-on stacking adaptability: an STM/STS study of 1D nanowires assembled via rotatable ethynyls [J].
Lee, Shern-Long ;
Wu, Hung-Jen ;
Hsu, Yu-Ju ;
Chen, Hsiu-Hui ;
Hsu, Hsiu-Fu ;
Chen, Chun-hsien .
CHEMICAL COMMUNICATIONS, 2014, 50 (91) :14093-14096