A Viewpoint on Chemical Reductions of Carbon-Oxygen Bonds in Renewable Feedstocks Including CO2 and Biomass

被引：70

作者：

Chauvier, Clement ^{[1
]}

Cantat, Thibault ^{[1
]}

机构：

[1] Univ Paris Saclay, NIMBE, CEA, CNRS,CEA Saclay, F-91191 Gif Sur Yvette, France

来源：

ACS CATALYSIS | 2017年 / 7卷 / 03期

基金：

欧洲研究理事会;

关键词：

FORMIC-ACID; ELECTROCHEMICAL REDUCTION; CATALYZED HYDROGENATION; AROMATIC-AMINES; NAD(P)H MODEL; DIOXIDE; METHANOL; DEHYDROGENATION; ESTERS; CONVERSION;

D O I：

10.1021/acscatal.6b03581

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The utilization of renewable carbon feedstocks e.g. CO2 or biomass for the production of fuels and chemicals presents challenges in chemistry and catalysis. This article discusses how current reduction methods and reductants able to cleave σ and Π C-O bonds by hydride transfer can be utilized for the conversion of organic compounds deriving from CO2 biomass or waste plastics. The successes pitfalls and challenges in the field are considered within the framework of sustainable chemistry.

引用

页码：2107 / 2115

页数：9

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