Indirect spectrophotometric determination of sulphides with N,N-dietylaniline

被引：0

作者：

Zaporozhets, O. A. ^{[1
]}

Pogrebnyak, O. S. ^{[1
]}

Paustovska, A. S. ^{[1
]}

机构：

[1] Shevchenko Natl Univ, Kiev, Ukraine

来源：

JOURNAL OF WATER CHEMISTRY AND TECHNOLOGY | 2015年 / 37卷 / 06期

关键词：

bromate; bromide; N; N-diethylaniline; spectrophotometry; sulfide;

D O I：

10.3103/S1063455X15060053

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Proposed is the technique of spectrophotometric determination of sulfide in the range 0.05-1.50 mg/dm(3) based on oxidation of it in the sulfate medium by the known excess of bromate followed by subsequent oxidation of N,N-diethylaniline in the presence of the excess of bromide and photometering at 226 nm of 4-bromo-N,N-dietylaniline being formed. The sulfide detection limit constitutes 0.03 mg/dm(3). Metrological characteristics of the technique were checked by way of determination of sulfide in waters in ballneotherapy (mud, silt, etc.).

引用

页码：289 / 294

页数：6

共 16 条

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