Synthesis of self-doped conducting polyaniline bearing phosphonic acid monoester

被引：18

作者：

Amaya, Toru ^{[1
]}

Abe, Yasushi ^{[1
,2
]}

Inada, Yuhi ^{[1
]}

Hirao, Toshikazu ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] Daihachi Chem Ind Co Ltd, Osaka R&D Lab, Higashiosaka, Osaka 5770056, Japan

来源：

SYNTHETIC METALS | 2014年 / 195卷

关键词：

Polyaniline; Conductive polymer; Self-doping; Poly(aniline phosphonic acid); Phosphonic acid monoester; POLY(O-AMINOBENZYLPHOSPHONIC ACID); POLYMERS;

D O I：

10.1016/j.synthmet.2014.05.021

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Poly(2-methoxyaniline-5-phosphonic acid monoethyl ester) (PMAPE) was synthesized via oxidative polymerization of 2-methoxyaniline-5-phosphonic acid monoethyl ester. This is the first example of the conducting self-doped polymers with phosphonic acid monoester. Self-doping of the polymer was shown by UV-vis-NIR and ESR measurements. The pyridinium salt of the thus-obtained PMAPE was water-soluble and its film exhibited conductivity. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：137 / 140

页数：4

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