Effect of electrolytes nature and concentration on the morphology and structure of MoS2 nanomaterials prepared using one-pot solvothermal method

被引：30

作者：

Akram, H. ^{[1
,3
]}

Mateos-Pedrero, C. ^{[4
]}

Gallegos-Suarez, E. ^{[1
,2
]}

Guerrero-Ruiz, A. ^{[1
,2
]}

Chafik, T. ^{[3
]}

Rodriguez-Ramos, I. ^{[1
,2
]}

机构：

[1] CSIC, Inst Catalisis & Petroleoquim, E-28049 Madrid, Spain

[2] CSIC, Unidad Asociada UNED ICP, Grp Diseno & Aplicac Catalizadores Heterogeneos, Madrid, Spain

[3] Univ Abdelmalek Essaadi, Fac Sci & Tech Tanger, Lab Genie Chim & Valorisat Ressources, Tangier, Morocco

[4] Univ Porto, Fac Engn, Lab Proc Engn Environm Biotechnol & Energy, P-4200465 Oporto, Portugal

来源：

APPLIED SURFACE SCIENCE | 2014年 / 307卷

关键词：

MoS2; Solvothermal synthesis; Nanotubes; Nanospheres; Electrolyte; Ionic strength; TEMPERATURE; ROUTE;

D O I：

10.1016/j.apsusc.2014.04.034

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Different MoS2 nanostructures have been obtained following an innovative one-step solvothermal method by changing the concentration and type of the electrolyte while avoiding the use of surfactant. It was found that the chemical nature of the studied electrolyte ((NH4)(2)CO3 or KG) do not significantly affect the morphology and structure of the obtained MoS2 nanomaterials. Nevertheless, increasing the electrolyte concentration yields to a remarkable modification of the morphology of the resulting MoS2 from nanospheres to worm-shaped then finally to nanotubes. All the obtained nanomaterials were characterized by X-ray diffraction, (XRD), transmission electron microscopy (TEM, HRTEM), Fourier transformation infra-red spectroscopy (FTIR), thermogravimetric analysis (TGA) and X-ray photoelectron spectroscopy (XPS). (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：319 / 326

页数：8

共 36 条

[1] Molybdenum polysulfide hollow microtubules grown at room temperature from solution [J].