Carbon-based solid acid: an efficient and reusable catalyst for the diastereoselective ring opening reaction of α-epoxyketones

被引：4

作者：

Saffar-Teluri, Ali ^{[1
]}

机构：

[1] Islamic Azad Univ, Fac Mat Sci & Engn, Najafabad Branch, Najafabad, Iran

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2014年 / 40卷 / 02期

关键词：

Epoxyketones; Carbon-based solid acid; Diastereoselective; Ring opening; TRANSFER CHAIN ISOMERIZATION; ELECTRON-TRANSFER REACTIONS; O BOND-CLEAVAGE; ALPHA; BETA-EPOXY KETONES; EPOXIDE RINGS; WATER;

D O I：

10.1007/s11164-012-0979-x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon-based solid acid efficiently catalyzes diastereoselective ring opening of alpha-epoxyketones in the presence of methanol to produce the corresponding alpha-hydroxy-beta-methoxyketones in excellent yield.

引用

页码：523 / 529

页数：7

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