Hydrothermal synthesis and characterization of a new inorganic-organic hybrid layered zinc phosphate-phosphite (C6H15N2)2Zn4(PO4)2(HPO3)2

被引：51

作者：

Wang, Y ^{[1
]}

Yu, JH ^{[1
]}

Du, Y ^{[1
]}

Shi, Z ^{[1
]}

Zou, YC ^{[1
]}

Xu, RR ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / Royal Society of Chemistry卷 / 21期

关键词：

D O I：

10.1039/b204876k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Using H3PO3 or H3PO2 as a phosphorus source, the first inorganic-organic hybrid layered zinc phosphate-phosphite (C6H15N2)(2)Zn-4 (PO4)(2) (HPO3)(2) (denoted ZnPO-CJ12) has been hydrothermally synthesized in the presence of 1,2-diaminocyclohexane (DACH) as a structure-directing agent. Single-crystal X-ray diffraction analysis shows that its structure is made up of inorganic-organic hybrid sheets containing both PO43- and HPO32- anions. Only the trans-isomers are involved in the structure even though a mix of trans- and cis-isomers of DACH molecules are added in the reaction mixture. The hydrophobic ends of the DACH molecules exclusively protrude into the interlayer region.

引用

页码：4060 / 4063

页数：4

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