The thermal property of lead-free Sn-8.55Zn-1Ag-XAI solder alloys and their wetting interaction with Cu

被引:48
作者
Cheng, SC [1 ]
Lin, KL [1 ]
机构
[1] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 70101, Taiwan
关键词
wettability; lead-free solder; Sn-Zn; solidus temperature; liquidus temperature; wetting force; wetting time; intermetallics;
D O I
10.1007/s11664-002-0187-3
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
The wetting behaviors between the quaternary Sn-8.55Zn-1Ag-XAl solder alloys and Cu have been investigated with the wetting balance method. The Al contents, x, of the quaternary solder alloys investigated were 0.01-0.45 wt.%. The results of differential scanning calorimeter (DSC) analysis indicate that the solders exhibit a solid-liquid coexisting range of about 7-10degreesC. The solidus temperature of the quaternary Sn-8.55Zn-1Ag-XAl solder alloys is about 198.2degreesC, while the liquidus temperatures are 205-207degreesC. The experimental results showed that the wettability of the Sn-8.55Zn-1Ag-XAl solder alloys is improved by the addition of Al. The mean maximum wetting force of the solders with Cu is within 0.75-1.18 mN and the mean wetting time is around 1.0-1.1 sec, better than the similar to1.3 sec of eutectic Sn-9Zn and Sn-8.55Zn-1Ag solder alloys. The addition of Al also depresses the formation of epsilon-Ag-Zn compounds at the interface between Sn-8.55Zn-1Ag-XAl solders and copper.
引用
收藏
页码:940 / 945
页数:6
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