Crystal engineering, solid state spectroscopy and time-resolved diffraction

被引:39
作者
Coppens, P [1 ]
Ma, BQ [1 ]
Gerlits, O [1 ]
Zhang, YG [1 ]
Kulshrestha, P [1 ]
机构
[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA
关键词
D O I
10.1039/b203602a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The use of calixarene-based supramolecular solids in spectroscopy and time-resolved crystallography is discussed. A series of solids with, as guests, benzophenone, benzil, decamethylruthenocene and a binuclear Rh cationic complex have been synthesized and analyzed. The excited state lifetimes that have been measured show a pronounced dependence on the molecular environment. © 2002 The Royal Society of Chemistry.
引用
收藏
页码:302 / 309
页数:8
相关论文
共 48 条
[1]   CHEMISTRY OF CYCLOPENTADIENYL-RUTHENIUM AND CYCLOPENTADIENYL-OSMIUM COMPLEXES .3. NEW HIGH-YIELD SYNTHESES OF RUTHENOCENES AND OSMOCENES - THE CRYSTAL AND MOLECULAR-STRUCTURES OF DECAMETHYLRUTHENOCENE [RU(ETA-5-C5ME5)2] AND DECAMETHYLOSMOCENE [OS(ETA-5-C5ME5)2] [J].
ALBERS, MO ;
LILES, DC ;
ROBINSON, DJ ;
SHAVER, A ;
SINGLETON, E ;
WIEGE, MB ;
BOEYENS, JCA ;
LEVENDIS, DC .
ORGANOMETALLICS, 1986, 5 (11) :2321-2327
[3]   PHOSPHORESCENCE MICROWAVE DOUBLE-RESONANCE STUDIES ON THE SHARP PHOSPHORESCENCE SPECTRUM OF BENZIL IN A METHYLCYCLOHEXANE MATRIX - EVIDENCE FOR THE TRANS-PLANAR TRIPLET STRUCTURE [J].
ASANO, K ;
AITA, S ;
AZUMI, T .
JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (23) :5538-5541
[4]   Metal sulfonatocalix[4,5]arene complexes: bi-layers, capsules, spheres, tubular arrays and beyond [J].
Atwood, JL ;
Barbour, LJ ;
Hardie, MJ ;
Raston, CL .
COORDINATION CHEMISTRY REVIEWS, 2001, 222 :3-32
[5]   2ND-SPHERE COORDINATION OF TRANSITION-METAL COMPLEXES BY CALIX[4]ARENES [J].
ATWOOD, JL ;
ORR, GW ;
HAMADA, F ;
VINCENT, RL ;
BOTT, SG ;
ROBINSON, KD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (07) :2760-2761
[6]   Diffuse reflectance laser-flash photolytic study of aromatic ketones within calixarene solid matrices [J].
Barra, M ;
Agha, KA .
SUPRAMOLECULAR CHEMISTRY, 1998, 10 (02) :91-95
[7]   The 20 K structure of p-amino-p′-nitrobiphenyl in the non-constraining environment of its β-cyclodextrin inclusion complex [J].
Brett, TJ ;
Liu, SC ;
Coppens, P ;
Stezowski, JJ .
CHEMICAL COMMUNICATIONS, 1999, (06) :551-552
[8]  
Cave GWV, 2001, EUR J ORG CHEM, V2001, P3227
[9]   ZERO-FIELD MAGNETIC-RESONANCE STUDY ON PHOSPHORESCENT TRIPLET-STATE OF BENZIL [J].
CHAN, IY ;
NELSON, BN .
JOURNAL OF CHEMICAL PHYSICS, 1975, 62 (10) :4080-4088
[10]   ENDOR STUDY OF THE GEOMETRY OF THE LOWEST TRIPLET-STATE OF BENZIL [J].
CHAN, IY ;
HEATH, BA .
JOURNAL OF CHEMICAL PHYSICS, 1979, 71 (03) :1070-1078