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PREPARATION AND CHARACTERIZATION OF SILVER NANOPARTICLES/CARBON NANOFIBERS VIA ELECTROSPINNING WITH RESEARCH ON THEIR CATALYTIC PROPERTIES
被引:5
作者:
Liu, Huan
[1
]
Bai, Jie
[1
]
Wang, Qi
[1
]
Li, Chunping
[1
]
Wang, Shan
[1
]
Sun, Weiyan
[1
]
Huang, Yarong
[1
]
机构:
[1] Inner Mongolia Univ Technol, Chem Engn Coll, Huhhote 010051, Peoples R China
来源:
基金:
中国国家自然科学基金;
关键词:
Electrospinning;
Ag nanoparticles;
carbon nanofibers;
catalytic;
styrene epoxidation;
ELECTRODE PERFORMANCE ANODES;
DOUBLE PROTECTION STRATEGY;
PROPENE EPOXIDATION;
CARBON NANOFIBERS;
STYRENE OXIDE;
PROPYLENE;
IMPROVE;
OXYGEN;
SIZE;
PAN;
D O I:
10.1142/S1793292014500416
中图分类号:
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
Ag nanoparticles (Ag NPs) embedded carbon nanofibers (CNFs) were prepared by a new route which included chemical reaction process, electrospinning and calcination technique. The morphology and structure of the composite nanofibers were investigated by scanning electron microscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy and X-ray diffraction. It indicated that Ag NPs were uniformly distributed in the CNFs. This effective synthesis method can be used to prepare other composite nanofibers with functionality. The Ag NPs/CNFs that served as supported catalysts were used in the styrene epoxidation by TBHP. The Ag NPs/CNFs catalyst showed its highly catalytic activity for the epoxidation of styrene (conversion: 40.6%, SO selectivity: 35.9%). This kind of composite nanofiber membrane was proved effectively catalytic activity and recycled easily in the styrene epoxidation.
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页数:7
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