Synthesis of the stable UO2I2, the last of the uranyl dihalides.: X-Ray crystal structure of [UO2I2(py)3]

被引：58

作者：

Berthet, JC ^{[1
]}

Nierlich, M ^{[1
]}

Ephritikhine, M ^{[1
]}

机构：

[1] CEA Saclay, Serv Chim Mol, DSM, DRECAM,CNRS URA 331, F-91191 Gif Sur Yvette, France

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 07期

关键词：

D O I：

10.1039/b400717d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment Of UO2(OTf)(2) with pure Me3SiI led to the quantitative formation Of UO2I2 (1). This compound dissolved in pyridine and thf to give the red adducts [UO2I2L3] {L = py (2) or thf (3)), which were also obtained from the metathetical reaction Of UO2(OTf)(2) and KI. The crystal structure of 2 has been determined. The uranyl diiodide complexes 1-3 are thermally quite stable, providing that strictly anhydrous conditions are employed.

引用

页码：870 / 871

页数：2

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