Synthesis of macrocyclic arylene ketone oligomers containing the phthaloyl moiety by Friedel-crafts acylation reaction

被引:6
|
作者
Guo, QZ [1 ]
Bo, SQ [1 ]
Chen, TL [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
关键词
D O I
10.1246/cl.2004.414
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two kinds of macrocyclic arylene ketone oligomers have been synthesized in high yield from phthaloyl dichloride and various bridge-linking electron-rich aromatic hydrocarbons via the modified Friedel-Crafts acylation reaction. The presence of a Lewis base in this reaction is demonstrated to be advantageous for forming macrocycle oligomers. These resultant oligomers can undergo melt ring-opening polymerization to give polymers with high T. and excellent thermal stability.
引用
收藏
页码:414 / 415
页数:2
相关论文
共 50 条
  • [31] Polymerization behaviors of poly(ether ketone) via Friedel-Crafts acylation.
    Sakaguchi, Y
    Kimura, K
    Omori, M
    Yamashita, Y
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U303 - U303
  • [32] Synthesis and polymerization of some macrocyclic (arylene ether sulfone) containing cardo groups and macrocyclic (arylene ether ketone sulfone) oligomers
    Jiang, HY
    Chen, TL
    Bo, SQ
    Xu, JP
    POLYMER, 1998, 39 (24) : 6079 - 6083
  • [33] Facile synthesis of pivalophenones by an ultrasound assisted iodine catalysed Friedel-Crafts acylation reaction
    Gopalakrishnan, G
    Anandhi, S
    Narasimhan, NS
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1996, 35 (11): : 1197 - 1198
  • [34] Friedel-Crafts acylation and metalation strategies in the synthesis of calothrixins A and B
    Bernardo, PH
    Chai, CLL
    JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (23): : 8906 - 8909
  • [35] SYNTHESIS OF KETONIC INDOLES BY FRIEDEL-CRAFTS REACTION
    ROSSEELS, G
    PEIREN, M
    MATTEAZZI, J
    WOUTERS, G
    PROST, M
    BULLETIN DES SOCIETES CHIMIQUES BELGES, 1975, 84 (03): : 263 - 265
  • [36] FRIEDEL-CRAFTS ACYLATION REACTION .2. A STUDY OF HAMMETT RELATIONSHIP IN FRIEDEL-CRAFTS BENZOYLATION OF TOLUENE WITH SUBSTITUTED BENZOYL CHLORIDES
    SLOOTMAEKERS, PJ
    RASSCHAE.A
    JANSSENS, W
    BULLETIN DES SOCIETES CHIMIQUES BELGES, 1966, 75 (3-4): : 199 - +
  • [38] Comparison of metallic chlorides as catalysts for the Friedel-Crafts ketone synthesis
    Dermer, OC
    Wilson, DM
    Johnson, FM
    Dermer, VH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1941, 63 : 2881 - 2883
  • [39] TITANIUM TETRACHLORIDE AS A CATALYST IN THE FRIEDEL-CRAFTS REACTION .1. ACYLATION
    CULLINANE, NM
    CHARD, SJ
    LEYSHON, DM
    JOURNAL OF THE CHEMICAL SOCIETY, 1952, (FEB): : 376 - 380