The role of carbonate as a catalyst of Fenton-like reactions in AOP processes: CO3•- as the active intermediate

被引：31

作者：

Burg, Ariela ^{[1
]}

Shamir, Dror ^{[2
]}

Shusterman, Inna ^{[3
]}

Kornweitz, Haya ^{[4
]}

Meyerstein, Dan ^{[3
,4
]}

机构：

[1] SCE, Dept Chem Engn, Beer Sheva, Israel

[2] Nucl Res Ctr Negev, IL-84190 Beer Sheva, Israel

[3] Ben Gurion Univ Negev, Dept Chem, IL-84105 Beer Sheva, Israel

[4] Ariel Univ, Dept Biol Chem, Ariel, Israel

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 86期

关键词：

ORANGE II DEGRADATION; OXIDATIVE-DEGRADATION; HYDROGEN-PEROXIDE; AMBIENT CONDITIONS; ORGANIC-DYES; METAL-ION; H2O2; COMPLEXES; MECHANISM; SYSTEM;

D O I：

10.1039/c4cc05852f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetic and DFT results for the carbonate catalysed Co(H2O)(6)(2+) + H2O2 Fenton-like reaction suggest a mechanism involving the formation of a cyclic transient, cyclic-(CO4)Co-II(OOH)(H2O)(2)(-) that decomposes into Co-II(H2O)(OOH)(OH)(2) + CO3 center dot-, i.e. no OH center dot radicals are involved. Plausible biological implications are pointed out.

引用

页码：13096 / 13099

页数：4

共 40 条

[1] Ang Z., 2012, IND ENG CHEM RES, V51, P11104
[2] Degradation of organic contaminants in water with sulfate radicals generated by the conjunction of peroxymonosulfate with cobalt
Anipsitakis, GP
Dionysiou, DD
[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2003, 37 (20) : 4790 - 4797
[3] Kinetics and Mechanism of Peroxymonocarbonate Formation
Bakhmutova-Albert, Ekaterina V.
Yao, Huirong
Denevan, Daniel E.
Richardson, David E.
[J]. INORGANIC CHEMISTRY, 2010, 49 (24) : 11287 - 11296
[4] Three H2O2 molecules are involved in the "Fenton-like" reaction between Co(H2O)62+ and H2O2
Burg, Ariela
Shusterman, Inna
Kornweitz, Haya
Meyerstein, Dan
[J]. DALTON TRANSACTIONS, 2014, 43 (24) : 9111 - 9115
[5] Superoxide Dismutase Administration, A Potential Therapy Against Oxidative Stress Related Diseases: Several Routes of Supplementation and Proposal of an Original Mechanism of Action
Carillon, Julie
Rouanet, Jean-Max
Cristol, Jean-Paul
Brion, Richard
[J]. PHARMACEUTICAL RESEARCH, 2013, 30 (11) : 2718 - 2728
[6] High performance of a simple cobalt(II)-monoethanolamine complex for orange II degradation with H2O2 as an oxidant at ambient conditions
Chen, Min
Peng, Kaiyuan
Wang, Hong
Yang, Zhen
Zeng, Qingfu
Xu, Aihua
[J]. CHEMICAL ENGINEERING JOURNAL, 2012, 197 : 110 - 115
[7] Efficient H2O2 Oxidation of Organic Dyes Catalyzed by Simple Copper(II) Ions in Bicarbonate Aqueous Solution
Cheng, Long
Wei, Mingyu
Huang, Lianghua
Pan, Fei
Xia, Dongsheng
Li, Xiaoxia
Xu, Aihua
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (09) : 3478 - 3485
[8] INORGANIC COBALT SPECIES IN SEA-WATER
COSOVIC, B
DEGOBBIS, D
BILINSKI, H
BRANICA, M
[J]. GEOCHIMICA ET COSMOCHIMICA ACTA, 1982, 46 (02) : 151 - 158
[9] THE RELATION OF SERUM BICARBONATE CONCENTRATION TO MUSCLE COMPOSITION
DARROW, DC
SCHWARTZ, R
IANNUCCI, JF
COVILLE, F
[J]. JOURNAL OF CLINICAL INVESTIGATION, 1948, 27 (02) : 198 - 208
[10] MnII-A fascinating oxidation catalyst: Mechanistic insight into the catalyzed oxidative degradation of organic dyes by H2O2
Ember, Erika
Gazzaz, Hanaa Asaad
Rothbart, Sabine
Puchta, Ralph
van Eldik, Rudi
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2010, 95 (3-4) : 179 - 191

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