Au/TiO2 nanotube catalysts prepared by combining sol-gel method with hydrothermal treatment and their catalytic properties for CO oxidation

被引:16
作者
Zhao, Hang [1 ,2 ]
Zhang, Ping [1 ,2 ]
Wang, Yudong [1 ,2 ]
Huang, Weiping [1 ,2 ]
Zhang, Shoumin [1 ,2 ]
机构
[1] Nankai Univ, Dept Chem, Key Lab Adv Energy Mat Chem, MOE, Tianjin 300071, Peoples R China
[2] Nankai Univ, TKL Met & Mol Based Mat Chem, Tianjin 300071, Peoples R China
基金
中国国家自然科学基金;
关键词
Gold; TiO2; nanotubes; Sol-gel; CO oxidation; GOLD NANOPARTICLES; TIO2; NANOTUBES; SUPPORTED GOLD; DEPOSITION-PRECIPITATION; FORMATION MECHANISM; TITANATE NANOTUBES; CARBON-MONOXIDE; PARTICLES; CLUSTERS; TEMPERATURE;
D O I
10.1007/s10971-014-3390-9
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A new preparation method for Au/TiO2 nanotubes (NTs) by combing sol-gel with hydrothermal treatment technique was developed. The TiO2 NTs calcined at 300 A degrees C were nearly uniform, and the gold particles were distributed homogeneously. The possible formation mechanism was suggested. The 5 % Au/TiO2 NTs calcined at 300 A degrees C had the best catalytic activity for CO oxidation, and their conversion of CO remained at 100 % during 60 h on stream. This preparation method could improve the thermal stability of Au/TiO2 nanotube catalysts.
引用
收藏
页码:406 / 412
页数:7
相关论文
共 44 条
[1]   Transmission electron microscopy observation of the structure of TiO2 nanotube and Au/TiO2 nanotube catalyst [J].
Akita, T ;
Okumura, M ;
Tanaka, K ;
Ohkuma, K ;
Kohyama, M ;
Koyanagi, T ;
Date, M ;
Tsubota, S ;
Haruta, M .
SURFACE AND INTERFACE ANALYSIS, 2005, 37 (02) :265-269
[2]   A review on catalytic applications of Au/TiO2 nanoparticles in the removal of water pollutant [J].
Ayati, Ali ;
Ahmadpour, Ali ;
Bamoharram, Fatemeh F. ;
Tanhaei, Bahareh ;
Manttari, Mika ;
Sillanpaa, Mika .
CHEMOSPHERE, 2014, 107 :163-174
[3]   The effect of hydrothermal conditions on the mesoporous structure of TiO2 nanotubes [J].
Bavykin, DV ;
Parmon, VN ;
Lapkin, AA ;
Walsh, FC .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (22) :3370-3377
[4]   Oxidation-resistant gold-55 clusters [J].
Boyen, HG ;
Kästle, G ;
Weigl, F ;
Koslowski, B ;
Dietrich, C ;
Ziemann, P ;
Spatz, JP ;
Riethmüller, S ;
Hartmann, C ;
Möller, M ;
Schmid, G ;
Garnier, MG ;
Oelhafen, P .
SCIENCE, 2002, 297 (5586) :1533-1536
[5]   Gold nanoparticle synthesis in graft copolymer micelles [J].
Carrot, G ;
Valmalette, JC ;
Plummer, CJG ;
Scholz, SM ;
Dutta, J ;
Hofmann, H ;
Hilborn, JG .
COLLOID AND POLYMER SCIENCE, 1998, 276 (10) :853-859
[6]   TEM study on the formation mechanism of sodium titanate nanotubes [J].
Chen, Weiping ;
Guo, Xinyong ;
Zhang, Shunli ;
Jin, Zhensheng .
JOURNAL OF NANOPARTICLE RESEARCH, 2007, 9 (06) :1173-1180
[7]   Preparation and characterization of nanosized Pt/Au particles on TiO2-nanotubes [J].
Chien, SH ;
Liou, YC ;
Kuo, MC .
SYNTHETIC METALS, 2005, 152 (1-3) :333-336
[8]   Support effect in high activity gold catalysts for CO oxidation [J].
Comotti, M ;
Li, WC ;
Spliethoff, B ;
Schüth, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (03) :917-924
[9]   Supported gold nanoparticles as catalysts for organic reactions [J].
Corma, Avelino ;
Garcia, Hermenegildo .
CHEMICAL SOCIETY REVIEWS, 2008, 37 (09) :2096-2126
[10]   Gold nanoparticles: Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology [J].
Daniel, MC ;
Astruc, D .
CHEMICAL REVIEWS, 2004, 104 (01) :293-346