Confession of a Magnesium Battery

被引：226

作者：

Bucur, Claudiu B. ^{[1
]}

Gregory, Thomas ^{[2
]}

Oliver, Allen G. ^{[3
]}

Muldoon, John ^{[1
]}

机构：

[1] Toyota Res Inst North Amer, Ann Arbor, MI 48105 USA

[2] Borealis Technol Solut LLC, Midland, MI 48642 USA

[3] Univ Notre Dame, Notre Dame, IN 46556 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2015年 / 6卷 / 18期

关键词：

WIDE ELECTROCHEMICAL WINDOWS; RECHARGEABLE MG BATTERIES; ELECTROLYTE-SOLUTIONS; REVERSIBLE MAGNESIUM; INSERTION; CATHODE; LITHIUM; INTERCALATION; V2O5; COMPLEX;

D O I：

10.1021/acs.jpclett.5b01219

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Magnesium is an ideal metal anode that has nearly double the volumetric capacity of lithium metal with a very negative reduction potential of -2.37 vs SHE. A significant advantage of magnesium is the apparent lack of dendrite formation during charging, which overcomes major safety and performance challenges encountered with using lithium metal anodes. Here, we highlight major recent advances in nonaqueous Mg electrochemistry, notably the development of electrolytes and cathodes, and discuss some of the challenges that must be overcome to realize a practical magnesium battery.

引用

页码：3578 / 3591

页数：14

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