CuO Nanoparticles with Leaf-Like Microstructure-A Powerful Nonenzymatic Glucose Sensor

被引：0

作者：

Karunakaran, Chockalingam ^{[1
]}

Manikandan, Govindasamy ^{[1
]}

Gomathisankar, Paramasivan ^{[1
]}

机构：

[1] Annamalai Univ, Dept Chem, Annamalainagar 608002, Tamil Nadu, India

来源：

SENSOR LETTERS | 2013年 / 11卷 / 08期

关键词：

Electrochemical Analysis; Nanomaterial; Microwave Synthesis; Morphology; GAS-SENSING PROPERTIES; LITHIUM-ION BATTERIES; COPPER-OXIDE; CARBON ELECTRODE; BIOSENSOR; NANOSTRUCTURES; NANOTUBES; LIQUID; FILMS; ARRAY;

D O I：

10.1166/sl.2013.2940

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

CuO nanoparticles with leaf-like microstructure have been obtained by cetyltrimethylammonium bromide-assisted microwave synthesis. They have been characterized by powder X-ray and selected area electron diffractions, scanning and transmission electron microscopies and energy dispersive X-ray and electrochemical impedance spectroscopies. The synthesized leaf-like CuO deposited on graphite electrode nonenzymatically senses glucose efficiently. Cyclic voltammetic and chronoamperometric studies reveal the excellent electrocatalytic activity of leaf-like CuO towards direct glucose oxidation. The leaf-like CuO exhibits very high sensitivity (17.3 mu A mu M-1 cm(-2)) towards amperonnetric determination of glucose and glucose as low as 2 mu M could be estimated.

引用

页码：1478 / 1483

页数：6

共 40 条

[1] CuO Nanopetals Based Electrochemical Sensor for Selective Ag+ Measurements [J].

Amin, G. ;

Asif, M. H. ;

Zainelabdin, A. ;

Zaman, S. ;

Nur, O. ;

Willander, M. .

SENSOR LETTERS, 2012, 10 (3-4) :754-759

[2] Emergent methods to synthesize and characterize semiconductor CuO nanoparticles with various morphologies - an overview [J].

Anandan, Sambandam ;

Yang, Shihe .

JOURNAL OF EXPERIMENTAL NANOSCIENCE, 2007, 2 (1-2) :23-56

[3] Copper oxide nanoparticle impurities are responsible for the electroanalytical detection of glucose seen using multiwalled carbon nanotubes [J].

Batchelor-McAuley, Christopher ;

Wildgoose, Gregory G. ;

Compton, Richard G. ;

Shao, Lidong ;

Green, Malcolm L. H. .

SENSORS AND ACTUATORS B-CHEMICAL, 2008, 132 (01) :356-360

[4] Controlled synthesis of copper nano/microstructures using ascorbic acid in aqueous CTAB solution [J].

Bicer, Mustafa ;

Sisman, Ilkay .

POWDER TECHNOLOGY, 2010, 198 (02) :279-284

[5]

Brad AJ., 2000, Electrochemical Methods: Fundamentals and Applications

[6] Hierarchical nanostructured copper oxide and its application in arsenic removal [J].

Cao, An-min ;

Monnell, Jason D. ;

Matranga, Christopher ;

Wu, Jia-min ;

Cao, Liang-liang ;

Gao, Di .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (50) :18624-18628

[7] Preparation, characterization, and electrochemical application of mesoporous copper oxide [J].

Cheng, Liang ;

Shao, Mingwang ;

Chen, Dayan ;

Zhang, Yuzhong .

MATERIALS RESEARCH BULLETIN, 2010, 45 (02) :235-239

[8] Disposable Biosensor for Measuring Sugars in Potatoes and Assessing Acrylamide Formation [J].

Creanga, C. ;

El Murr, N. .

SENSOR LETTERS, 2011, 9 (02) :612-615

[9] Controlled morphologies of copper oxide single crystalline nanostructures by wet chemistry and thermal decomposition processes [J].

Dong, Teng-Yuan ;

Chen, Chen-Ni ;

Cheng, Hsiu-Yi ;

Chen, Chiao-Pei ;

Jheng, Nai-Yuan .

INORGANICA CHIMICA ACTA, 2011, 367 (01) :158-165

[10] Electrochemical Biosensor of Glucose Based on the Immobilization of Glucose Oxidase on a Carbon Microsphere Modified Glassy Carbon Electrode [J].

Dong, Yong Ping ;

Huang, Li ;

Lei, Zhi Ping ;

Chu, Xiang Feng ;

Zhang, Qian Feng .

SENSOR LETTERS, 2012, 10 (3-4) :1024-1030

← 1 2 3 4 →