Friedel-Crafts type reaction of ferrocene with β-ketoesters

被引：12

作者：

Plazuk, D ^{[1
]}

Zakrzewski, J ^{[1
]}

机构：

[1] Univ Lodz, Dept Organ Chem, PL-90136 Lodz, Poland

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 24期

关键词：

D O I：

10.1021/jo025717e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of ferrocene with beta-ketoesters in the presence of BF3.Et2O or CF3SO3H affords beta-ferrocenyl-alpha, beta-unsaturated esters in 56-83% yield. In the case of alpha-unsubstituted-beta-ketoesters the reaction is totally E-stereoselective.

引用

页码：8672 / 8674

页数：3

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