Addition of organolithium compounds to tricarbonyl(tropone)iron complexes:: experimental and structural studies

被引：14

作者：

Coquerel, Y ^{[1
]}

Deprés, JP ^{[1
]}

Greene, AE ^{[1
]}

Philouze, C ^{[1
]}

机构：

[1] Univ Grenoble 1, LEDSS, F-38041 Grenoble, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 659卷 / 1-2期

关键词：

tricarbonyl(tropone)iron complexes; nucleophilic addition;

D O I：

10.1016/S0022-328X(02)01725-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The regioselectivity (1,2 vs. 1,4) in the nucleophilic addition of organolithium reagents to tropone(tricarbonyl)iron complexes has been studied and found to be correlated with the relative hardness of the nucleophile (HSAB principle). X-ray structures of several 1,2 and 1,4 adducts are reported. (C) 2002 Elsevier Science B.V. All rights reserved.

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收藏

页码：176 / 185

页数：10

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