S-trifluoromethyl esters of thiocarboxylic acids, RC(O)SCF3

被引：27

作者：

Kremlev, MM

Tyrra, W

Naumann, D

Yagupolskii, YL

机构：

[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany

[2] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02094 Kiev, Ukraine

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 32期

关键词：

S-trifluoromethyl esters; acid chlorides; halide substitution;

D O I：

10.1016/j.tetlet.2004.06.073

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

S-Trifluoromethyl esters of different types of thiocarboxylic acids have been prepared in moderate to excellent yields from halide Substitution reactions of the corresponding acid chlorides and tetramethylammonium trifluoromethylthiolate. C6F5C(O)SCF3 undergoes a surprising rearrangement on attempted isolation to give 4-CF3SC6F4C(O)F, which was converted into the corresponding acid. (C) 2004 Elsevier Ltd. All rights reserved.

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页码：6101 / 6104

页数：4

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