The dominant {001} facet-dependent enhanced visible-light photoactivity of ultrathin BiOBr nanosheets

被引：113

作者：

Chen, Jing ^{[1
]}

Guan, Meili ^{[2
,3
]}

Cai, Weizheng ^{[2
,3
]}

Guo, Jinju ^{[1
]}

Xiao, Chong ^{[2
,3
]}

Zhang, Gaoke ^{[1
]}

机构：

[1] Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei, Peoples R China

[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

[3] Univ Sci & Technol China, Collaborat Innovat Ctr Chem Energy Mat, Hefei 230026, Anhui, Peoples R China

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2014年 / 16卷 / 38期

基金：

中国博士后科学基金;

关键词：

PHOTOCATALYTIC ACTIVITY; HIGHLY EFFICIENT; ELECTRONIC-STRUCTURE; WATER; PHOTOREACTIVITY; DEGRADATION; TIO2; BR; CL;

D O I：

10.1039/c4cp02972k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ability to suppress the recombination of the photoinduced charges is the key prerequisite for an excellent photocatalyst, which has attracted extensive and continuous interest in the field of photocatalysis. Herein, we presented a convenient strategy for the one-step selective synthesis of ultrathin BiOBr nanosheets with atomic thickness through a simple solvothermal method. These ultrathin BiOBr nanosheets not only show high exposure percentage of active (001) facets but also have an optimized band structure, which synergistically facilitates the electron-hole pair separation to realize significantly promoted visible-light photocatalytic activity. Our results provide a new avenue and direction for the design of photocatalysts with high visible-light photocatalytic performance.

引用

页码：20909 / 20914

页数：6

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