Palladium(II) Recovery from Hydrochloric Acid Solutions by N,N′-Dimethyl-N,N′-Dibutylthiodiglycolamide

N,N′-dimethyl-N,N′-dibutylthiodiglycolamide (DMDBTDGA) has been synthesized, characterized, and is investigated in this work as a potential liquid-liquid extractant for palladium(II), platinum(IV), and rhodium(III) from hydrochloric acid solutions. Pd(II) is the only ion which is efficiently removed by DMDBTDGA in toluene from 1.5 M to 4.5 M HCl, but it is not extracted from 7.5 M HCl. Pd(II) stripping is quantitatively achieved by an acidic thiourea solution. Pd(II) extraction kinetics are highly favored (2–5 min). Distribution data points to a DMDBTDGA:Pd(II) species with a 1:1 molar ratio. Pd(II) can selectively be recovered by DMDBTDGA from 4.0 M HCl complex mixtures containing equivalent concentrations of Pt(IV) and Rh(III). When five-fold Fe(III) and Al(III) concentrations are present, only Pt(IV) in the presence of Fe(III), and Fe(III) itself, are extensively co-extracted together with Pd(II). However, Fe(III) can easily be eliminated through an intermediate scrubbing step with water. © 2015 by the authors.