Synthesis and Crystal Structure of Cobalt(II) Complex of 4,4′-Diamino-1-[(cyclohexa-2,4-dienyl)methyl]benzene

被引：0
|
作者：
Mei, Zhenhua [1 ]
Niu, Xiang [1 ]
Sun, Jie [1 ]
Qu, Bin [1 ]
机构：
[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2009年 / 21卷 / 03期
关键词：
Synthesis; Crystal structure; Cobalt(II) complex; 4,4 '-Diamino-1-[(cyclohexa-2,4-dienyl)methyl]benzene; DNA;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure of cobalt(II) complex of 4,4'-diamino-1-[(cyclohexa-2,4-dienyl)methyl]benzene has been determined by single crystal X-ray diffraction method. The crystal belongs to orthorhombic system, space group P-1 with unit cell constants a = 9.2500(8), b = 11.6619(10), c = 11.9660(11) angstrom, V = 1273.36(19) angstrom(3), Z = 1, Dc = 1.363 g/cm(3), mu = 0.406 mm(-1), F(000) = 550, R and wR are 0.0499 and 0.1498, respectively for 5981 unique reflections with 5095 observed reflections (I > 2 sigma(I)). In the crystal structure, molecules are linked into chains along the a axis by N-H center dot center dot center dot O intermolecular hydrogen bonds along the a axis.
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页码：2020 / 2026
页数：7
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